ArticleJournal of the American Chemical Society2019
Convergent Total Synthesis of Principinol D, a Rearranged Kaurane Diterpenoid.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 66 citations in OpenAlex.
- Regioselective Synthesis of Methyl Enol Ethers from Cycloalkanones via O-Methylation of Kinetic Enolates.Synthesis · 2026Article
- Enantioselective Synthesis of (+)-Auriculatol A.Journal of the American Chemical Society · 2025Article
- Synthesis of a Functionalized Bicyclo[3.2.1]Octane: A Common Subunit to Kauranes, Grayananes, and Gibberellanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Regioselective Synthesis of β,γ-Unsaturated Amides from Unactivated Alkenes.The Journal of organic chemistry · 2025Article
- Article
- Total Synthesis of the Diterpenes (+)-Randainin D and (+)-Barekoxide via Photoredox-Catalyzed Deoxygenative Allylation.Journal of the American Chemical Society · 2024Article
- Article
- Samarium(ii) iodide-mediated reactions applied to natural product total synthesis.RSC advances · 2022Review
- Total synthesis of grayanane natural products.Beilstein journal of organic chemistry · 2022Review
- Synthetic efforts toward the bicyclo[3.2.1]octane fragment of rhodojaponin III.Tetrahedron letters · 2021Article
- Enantioselective Total Synthesis of Andrographolide and 14-Hydroxy-Colladonin: Carbonyl Reductive Coupling and trans-Decalin Formation by Hydrogen Transfer.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
The total synthesis of principinol D, a rearranged kaurane diterpenoid, is reported. This grayanane natural product is constructed via a convergent fragment coupling approach, wherein the central seven-membered ring is synthesized at a late stage. The bicyclo[3.2.1]octane fragment is accessed by a Ni-catalyzed α-vinylation reaction. Strategic reductions include a diastereoselective SmI
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