ArticleFrontiers in chemistry2019
Elucidating Non-aqueous Solvent Stability and Associated Decomposition Mechanisms for Mg Energy Storage Applications From First-Principles.
Article in Frontiers in chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Tuning Solid Electrolyte Interphase Formation before Plating Onset in Anode-Free Sodium Batteries.JACS Au · 2026Article
- Effect of Thionation of the Carbonyl Groups in Naphthalimide-Phenoxazine Electron Donor-Acceptor Dyads on the Excited- State Dynamics: Transient Optical and Electron Paramagnetic Resonance Spectral Studies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Mg Plating in Nonethereal Electrolyte Solutions: Fact or Misconception?ChemSusChem · 2025Review
- Chemical Reaction Networks Explain Gas Evolution Mechanisms in Mg-Ion Batteries.Journal of the American Chemical Society · 2023Article
- Deciphering the Role of Fluoroethylene Carbonate towards Highly Reversible Sodium Metal Anodes.Research (Washington, D.C.) · 2022Article
- Toward practical issues: Identification and mitigation of the impurity effect in glyme solvents on the reversibility of Mg plating/stripping in Mg batteries.Frontiers in chemistry · 2022Article
- Electrodeposited PEDOT:PSS-AlPolymers · 2021Article
- A chemically consistent graph architecture for massive reaction networks applied to solid-electrolyte interphase formation.Chemical science · 2021Article
- Energy storage emerging: A perspective from the Joint Center for Energy Storage Research.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
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4 authors.
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Abstract
Rational design of novel electrolytes with enhanced functionality requires fundamental molecular-level understanding of structure-property relationships. Here we examine the suitability of a range of organic solvents for non-aqueous electrolytes in secondary magnesium batteries using density functional theory (DFT) calculations as well as experimental probes such as cyclic voltammetry and Raman spectroscopy. The solvents considered include ethereal solvents (e.g., glymes) sulfones (e.g., tetramethylene sulfone), and acetonitrile. Computed reduction potentials show that all solvents considered are stable against reduction by Mg metal. Additional computations were carried out to assess the stability of solvents in contact with partially reduced Mg cations (Mg
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