ArticleJournal of the American Chemical Society2019
Tuning the Circumference of Six-Porphyrin Nanorings.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed, 48 citations in OpenAlex.
- Template-directed self-assembly of porphyrin nanorings through an imine condensation reaction.Chemical science · 2025Article
- Symmetry-Breaking Charge-Separation in a Subphthalocyanine Dimer Resolved by Two-Dimensional Electronic Spectroscopy.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Highly Rigid, Yet Conformationally Adaptable, BisporphyrinJournal of the American Chemical Society · 2025Article
- β,β-Directly Linked Porphyrin Rings: Synthesis, Photophysical Properties, and Fullerene Binding.Journal of the American Chemical Society · 2023Article
- Strained Porphyrin Tape-Cycloparaphenylene Hybrid Nanorings.Organic letters · 2023Article
- A porphyrin pentamer as a bright emitter for NIR OLEDs.Journal of materials chemistry. C · 2022Article
- How Aromatic Are Molecular Nanorings? The Case of a Six-Porphyrin Nanoring*.Angewandte Chemie (International ed. in English) · 2021Article
- Twisted-Planar-Twisted expanded porphyrinoid dimer as a rudimentary reaction-based methanol indicator.Nature communications · 2020Article
- Spin Delocalization in the Radical Cations of Porphyrin Molecular Wires: A New Perspective on EPR Approaches.The journal of physical chemistry letters · 2019Article
Corrections and comments
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Authors and funding
9 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Most macrocycles are made from a simple repeat unit, resulting in high symmetry. Breaking this symmetry allows fine-tuning of the circumference, providing better control of the host-guest behavior and electronic structure. Here, we present the template-directed synthesis of two unsymmetrical cyclic porphyrin hexamers with both ethyne (C2) and butadiyne (C4) links, and we compare these nanorings with the symmetrical analogues with six ethyne or six butadiyne links. Inserting two extra carbon atoms into the smaller nanoring causes a spectacular change in binding behavior: the template affinity increases by a factor of 3 × 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.