ArticleJournal of the American Chemical Society2019
Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Low-energy photoredox catalysis.Nature reviews. Chemistry · 2025Review
- Volumetric Additive Manufacturing of Dicyclopentadiene by Solid-State Photopolymerization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- PhotoROMP: The Future Is Bright.ACS catalysis · 2024Review
- Article
- Triazole-modified Ru-carbene complexes: A valid olefin metathesis pre-catalyst for dynamic covalent chemistry via C=C bond formation.Chem catalysis · 2023Article
- Plasmonic visible-near infrared photothermal activation of olefin metathesis enabling photoresponsive materials.Nature chemistry · 2023Article
- Recent developments in visible light induced polymerization towards its application to nanopores.Chemical communications (Cambridge, England) · 2023Review
- Merging Grubbs second-generation catalyst with photocatalysis enablesChemical science · 2022Article
- Visible-Light-Initiated Palladium-Catalyzed Cross-coupling by PPhChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Hydrazone and Oxime Olefination via Ruthenium Alkylidenes.Angewandte Chemie (International ed. in English) · 2022Article
- The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition.Chemical science · 2022Article
- Continuous Additive Manufacturing using Olefin Metathesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Using Light to Modify the Selectivity of Transition Metal Catalysed Transformations.Angewandte Chemie (International ed. in English) · 2021Review
- Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium-Carbene Catalysts.Journal of the American Chemical Society · 2021Article
- Routes to High-Performing Ruthenium-Iodide Catalysts for Olefin Metathesis: Ligand Lability Is Key to Efficient Halide Exchange.Organometallics · 2021Article
- Photocatalyst-independent photoredox ring-opening polymerization ofChemical science · 2021Article
- The Impact of Water on Ru-Catalyzed Olefin Metathesis: Potent Deactivating Effects Even at Low Water Concentrations.ACS catalysis · 2021Article
- Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications.Accounts of chemical research · 2020Article
- Combining a ligand photogenerator and a Ru precatalyst: a photoinduced approach to cross-linked ROMP polymer films.RSC advances · 2019Article
Corrections and comments
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Authors and funding
3 authors.
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Abstract
Olefin metathesis is now one of the most efficient ways to create new carbon-carbon bonds. While most efforts focused on the development of ever-more efficient catalysts, a particular attention has recently been devoted to developing latent metathesis catalysts, inactive species that need an external stimulus to become active. This furnishes an increased control over the reaction which is crucial for applications in materials science. Here, we report our work on the development of a new system to achieve visible-light-controlled metathesis by merging olefin metathesis and photoredox catalysis. The combination of a ruthenium metathesis catalyst bearing two N-heterocyclic carbenes with an oxidizing pyrylium photocatalyst affords excellent temporal and spatial resolution using only visible light as stimulus. Applications of this system in synthesis, as well as in polymer patterning and photolithography with spatially resolved ring-opening metathesis polymerization, are described.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.