Evidence map›Paper›PMID 31007774›Full record

ArticleChemCatChem2018

Electrochemical and Kinetic Insights into Molecular Water Oxidation Catalysts Derived from Cp*Ir(pyridine-alkoxide) Complexes.

Emma V Sackville, Frank Marken, Ulrich Hintermair

Abstract read
In one paragraph

Article in ChemCatChem, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Identifying Bottlenecks in the Photocatalytic Oxygen Evolution Reaction with Covalent Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2025
    Article
  3. Strategies for Electrochemically Sustainable HAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022
    Review
  4. Article
  5. Article
  6. Article
  7. Graphite-protected CsPbBrNature communications · 2019
    Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Emma V SackvilleCentre for Sustainable Chemical Technologies University of Bath Claverton DownBath BA2 7AY United Kingdom.
Frank MarkenDepartment of Chemistry University of Bath Claverton Down Bath BA2 7AY United Kingdom.
Ulrich HintermairCentre for Sustainable Chemical Technologies University of Bath Claverton DownBath BA2 7AY United Kingdom.ORCID 0000-0001-6213-378X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We report the solution-phase electrochemistry of seven half-sandwich iridium(III) complexes with varying pyridine-alkoxide ligands to quantify electronic ligand effects that translate to their activity in catalytic water oxidation. Our results unify some previously reported electrochemical data of Cp*Ir complexes by showing how the solution speciation determines the electrochemical response: cationic complexes show over 1 V higher redox potentials that their neutral forms in a distinct demonstration of charge accumulation effects relevant to water oxidation. Building on previous work that analysed the activation behaviour of our pyalk-ligated Cp*Ir complexes

Indexed as

electrochemistryhomogeneous catalysisIridium complexespyridine-alkoxide ligandswater oxidation

Identifiers

PMID31007774
PMCPMC6470865

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.