Evidence map›Paper›PMID 31004318›Full record

ArticleOrigins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life2019

Prebiotic Syntheses Under Shock in the Water - Formamide - Potassium Bicarbonate - Sodium Hydroxide System.

Valery G Shtyrlin, Valery A Borissenok, Nikita Yu Serov, Vladimir G Simakov, Vyacheslav A Bragunets, Ivan R Trunin, Irina A Tereshkina, Sergey A Koshkin, Mikhail S Bukharov, Edward M Gilyazetdinov and 3 more

Abstract read
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In one paragraph

Article in Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
1.0field-weighted citation impact, top 23% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 6 citations in OpenAlex.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors at 3 institutions in 1 country.

Valery G ShtyrlinA.M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya St., 18, Kazan, Russian Federation, 420008. Valery.Shtyrlin@gmail.com.ORCID http://orcid.org/0000-0003-4820-884X
Valery A BorissenokSarov Physical Technical Institute, National Research Nuclear University "MEPhI" (Moscow Engineering Physics Institute), Dukhov St., 6, Sarov, Russian Federation, 607184.
Nikita Yu SerovA.M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya St., 18, Kazan, Russian Federation, 420008.
Vladimir G SimakovSarov Physical Technical Institute, National Research Nuclear University "MEPhI" (Moscow Engineering Physics Institute), Dukhov St., 6, Sarov, Russian Federation, 607184.
Vyacheslav A BragunetsRussian Federal Nuclear Center, All-Russian Research Institute of Experimental Physics, Mir Pr., 37, Sarov, Russian Federation, 607188.
Ivan R TruninSarov Physical Technical Institute, National Research Nuclear University "MEPhI" (Moscow Engineering Physics Institute), Dukhov St., 6, Sarov, Russian Federation, 607184.
Irina A TereshkinaSarov Physical Technical Institute, National Research Nuclear University "MEPhI" (Moscow Engineering Physics Institute), Dukhov St., 6, Sarov, Russian Federation, 607184.
Sergey A KoshkinA.M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya St., 18, Kazan, Russian Federation, 420008.
Mikhail S BukharovA.M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya St., 18, Kazan, Russian Federation, 420008.
Edward M GilyazetdinovA.M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya St., 18, Kazan, Russian Federation, 420008.
Evgeny E ShestakovSarov Physical Technical Institute, National Research Nuclear University "MEPhI" (Moscow Engineering Physics Institute), Dukhov St., 6, Sarov, Russian Federation, 607184.
Anna G SirotkinaSarov Physical Technical Institute, National Research Nuclear University "MEPhI" (Moscow Engineering Physics Institute), Dukhov St., 6, Sarov, Russian Federation, 607184.
Alexey V ZakharovA.M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya St., 18, Kazan, Russian Federation, 420008.
Kazan Federal University · RUAll-Russian Scientific Research Institute of Technical Physics · RUNational Research Nuclear University MEPhI · RU

Funding

Russian Foundation for Fundamental Investigations 17-03-00133
6 · The paper itself

Abstract

Syntheses under shock in nitrogen bubbled samples of the water - formamide - bicarbonate - sodium hydroxide system at pH 8.63, 9.46 and 10.44 were performed in the stainless steel preservation capsules. The maximum temperature and pressure in the capsules reached 545 K and 12.5 GPa respectively. Using the LC-MS-MS analysis, the 21 synthesis products have been identified, including amines and polyamines, carboxamide, acetamide and urea derivatives, compounds containing aniline, pyrrolidine, pyrrole, imidazole, as well as alcohol groups. It was found that the Fischer-Tropsch-type syntheses with catalysis on the surface of the stainless steel of the conservation capsule associated with the adsorbed hydrogen cyanide reactions and transamidation processes play the main role in the shock syntheses. Formation reactions of all the above-mentioned compounds have been suggested. It was proposed that hydrogen cyanide, ammonia, isocyanic acid, aminonitrile, aminoacetonitrile, as well as adsorbed species H

Indexed as

Evolution, ChemicalOrigin of LifeBicarbonatesChromatography, LiquidEarth, PlanetFormamidesHydrogen-Ion ConcentrationMeteoroidsPotassium CompoundsSodium HydroxideTandem Mass SpectrometryWaterBicarbonatesformamideFormamidespotassium bicarbonatePotassium CompoundsSodium HydroxideWaterBicarbonateFormamideHeterogeneous catalysisPrebiotic Fischer-Tropsch-type synthesesShock wave

Identifiers

PMID31004318
OpenAlexW2935780534

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.