ArticleChemical science2019
A chemical reaction controlled by light-activated molecular switches based on hetero-cyclopentanediyls.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Bond and Antibond Resonances: A Unified Framework for Singlet Biradical Character.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Reaction of NHOs with Bisphosphanes - Designing Diradicaloids, Zwitterions and Radicals.Angewandte Chemie (International ed. in English) · 2025Article
- Hemiphosphoindigos as a platform for chiroptical or water soluble photoswitching.Nature communications · 2025Article
- Isolation of a Staudinger-type Intermediate Utilizing a Five-Membered Phosphorus-Centered Biradicaloid.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Sequential radical and cationic reactivity at separated sites within one molecule in solution.Chemical science · 2024Article
- Radical Reactivity of the Biradical [⋅P(μ-NTer)Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Hyperpolarization Effects in Parahydrogen Activation with Pnictogen Biradicaloids: Metal-free PHIP and SABRE.Chemphyschem : a European journal of chemical physics and physical chemistry · 2021Article
- Azadiphosphaindane-1,3-diyls: A Class of Resonance-Stabilized Biradicals.Angewandte Chemie (International ed. in English) · 2021Article
- LED-NMR Monitoring of an Enantioselective Catalytic [2+2] Photocycloaddition.ChemPhotoChem · 2020Article
- A Systematic Survey of the Reactivity of Chlorinated NChemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Molecular switches are molecules that can reversibly be shifted between at least two stable states with different physical and chemical properties, making them interesting for application as chemical sensors or molecular machines. We recently discovered that five-membered, cyclic biradicals based on group 15 elements are efficient and robust photochemical switches that can be activated by red light. The quantum yield of the photo-isomerization is as high as 24.6%, and the thermal equilibration of the photo-activation product proceeds rapidly at ambient temperature. The fully reversible process was studied by experimental and high-level
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.