ArticleChemical science2019
Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
What it found
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Who cites it
27 citing papers in PubMed, 188 citations in OpenAlex.
- Enantioselective Vinyl Radical Addition to Aldehydes via Dual Chromium Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Enantioselective Contrathermodynamic Olefin Isomerization.Journal of the American Chemical Society · 2026Article
- Desilylative allylation of 3,3-borylsilylpropene under metallaphotoredox catalysis.Nature communications · 2026Article
- Unlocking Chromium Decarboxylative Ligand-to-Metal Charge Transfer: Efficient and Redox-Neutral Allylation of Aldehydes Using Carboxylic Acids.Journal of the American Chemical Society · 2025Article
- Photoredox/Nickel-Catalyzed Diastereoselective Allylation of Aldehydes with Morita-Baylis-Hillman Adducts.ACS catalysis · 2025Article
- Ion-Pair Hydrogen Atom Transfer Catalysis Enables Cr-Catalyzed Allylation of Ketones Using Hydrocarbon Alkenes.Angewandte Chemie (International ed. in English) · 2025Article
- Photoredox/Cr-catalyzed enantioselective radical-polar crossover transformation via C-H functionalization.Nature communications · 2025Article
- Organic Synthesis Away from Equilibrium: Contrathermodynamic Transformations Enabled by Excited-State Electron Transfer.Accounts of chemical research · 2024Article
- Visible-light-induced chemo-, diastereo- and enantioselective α-C(spChemical science · 2023Article
- Unlocking the Nucleophilicity of Strong Alkyl C-H Bonds via Cu/Cr Catalysis.ACS central science · 2023Article
- Designed Iron Catalysts for Allylic C-H Functionalization of Propylene and Simple Olefins.Angewandte Chemie (International ed. in English) · 2023Article
- Asymmetric 1,4-functionalization of 1,3-enynes via dual photoredox and chromium catalysis.Nature communications · 2022Article
- Decoding Key Transient Inter-Catalyst Interactions in a Reductive Metallaphotoredox-Catalyzed Allylation Reaction.Journal of the American Chemical Society · 2022Article
- Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.Chemical reviews · 2022Review
- Photoredox-Catalyzed C-H Functionalization Reactions.Chemical reviews · 2022Review
- Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.Chemical reviews · 2022Review
- Photoredox Propargylation of Aldehydes Catalytic in Titanium.The Journal of organic chemistry · 2021Article
- Photocatalytic three-component asymmetric sulfonylation via direct C(spNature communications · 2021Article
- Stereoinduction in Metallaphotoredox Catalysis.Angewandte Chemie (International ed. in English) · 2021Review
- Catalytic enantioselective C(spNature communications · 2021Review
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We describe a hybrid system that realizes cooperativity between an organophotoredox acridinium catalyst and a chiral chromium complex catalyst, thereby enabling unprecedented exploitation of unactivated hydrocarbon alkenes as precursors to chiral allylchromium nucleophiles for asymmetric allylation of aldehydes. The reaction proceeds under visible light irradiation at room temperature, affording the corresponding homoallylic alcohols with a diastereomeric ratio >20/1 and up to 99% ee. The addition of Mg(ClO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.