Evidence map›Paper›PMID 30983333›Full record

ArticleJournal of the American Chemical Society2019

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides.

David J P Kornfilt, David W C MacMillan

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 42 papers.

0numbers the graph read from it
0cells of the map it votes in
42citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

42 citing papers in PubMed.

  1. Article
  2. Article
  3. Harnessing COJournal of the American Chemical Society · 2026
    Article
  4. Article
  5. Trifluoromethylation of alkyl electrophiles withScience (New York, N.Y.) · 2025
    Article
  6. Review
  7. Copper-Photoredox-Catalyzed C(spAngewandte Chemie (International ed. in English) · 2025
    Article
  8. The Role of Electron Transfer in Copper-Mediated C(spAngewandte Chemie (International ed. in English) · 2025
    Article
  9. Article
  10. A facile synthesis of CFRSC advances · 2025
    Article
  11. Review
  12. CspACS catalysis · 2024
    Article
  13. Article
  14. Article
  15. Highly Enantioselective Decarboxylative Difluoromethylation.Journal of the American Chemical Society · 2024
    Article
  16. Article
  17. Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

David J P KornfiltMerck Center for Catalysis at Princeton University , Princeton , New Jersey 08544 , United States.
David W C MacMillanMerck Center for Catalysis at Princeton University , Princeton , New Jersey 08544 , United States.ORCID 0000-0001-6447-0587

Funding

Photoredox Catalysis in Organic ChemistryR01GM093213 · NIGMS · PRINCETON UNIVERSITY · PI MACMILLAN, DAVID W · 2010 to 2019
$3.0M
NIGMS NIH HHS R01 GM093213
6 · The paper itself

Abstract

Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to C

Indexed as

CatalysisCoordination ComplexesCopperHydrocarbons, BrominatedHydrocarbons, FluorinatedIridiumLightMethylationMolecular StructureOxidation-ReductionCoordination ComplexesCoppercupric chlorideHydrocarbons, BrominatedHydrocarbons, FluorinatedIridium

Identifiers

PMID30983333
PMCPMC7557108

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.