ArticleNature communications2019
Formation of colloidal alloy semiconductor CdTeSe magic-size clusters at room temperature.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Synthesis of Novel Stable ZnSe Magic-Sized Clusters and Their Direct Transformation to Quantum Dots.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Direct and Indirect Pathways of CdTeSe Magic-Size Cluster Isomerization Induced by Surface Ligands at Room Temperature.ACS central science · 2023Article
- Review
- Evolution of Photoluminescent CdS Magic-Size Clusters Assisted by Adding Small Molecules with Carboxylic Group.ACS omega · 2021Article
- Room-temperature formation of CdS magic-size clusters in aqueous solutions assisted by primary amines.Nature communications · 2020Article
Corrections and comments
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alloy semiconductor magic-size clusters (MSCs) have received scant attention and little is known about their formation pathway. Here, we report the synthesis of alloy CdTeSe MSC-399 (exhibiting sharp absorption peaking at 399 nm) at room temperature, together with an explanation of its formation pathway. The evolution of MSC-399 at room temperature is detected when two prenucleation-stage samples of binary CdTe and CdSe are mixed, which are transparent in optical absorption. For a reaction consisting of Cd, Te, and Se precursors, no MSC-399 is observed. Synchrotron-based in-situ small angle X-ray scattering (SAXS) suggests that the sizes of the two samples and their mixture are similar. We argue that substitution reactions take place after the two binary samples are mixed, which result in the formation of MSC-399 from its precursor compound (PC-399). The present study provides a room-temperature avenue to engineering alloy MSCs and an in-depth understanding of their probable formation pathway.
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Registered trials
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