ArticlePolymers2016
Modification of Thermal and Mechanical Properties of PEG-PPG-PEG Copolymer (F127) with MA-POSS.
Article in Polymers, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
16 citing papers in PubMed.
- Bioinspired Membranes with Silver Sulfadiazine and Piperine for Enhanced Cutaneous Permeability.ACS omega · 2025Article
- Dual-Functional Organosilicon Additives Containing Methacrylate and Trimethoxysilyl Groups Enhancing Impact Toughness of Polylactide (PLA): Structure-Property Relationship.Materials (Basel, Switzerland) · 2025Article
- Fortified electrospun collagen utilizing biocompatible Poly Glycerol Sebacate prepolymer (PGSp) and zink oxide nanoparticles (ZnO NPs) for diabetics wound healing: Physical, biological and animal studies.Regenerative therapy · 2024Article
- Research advances in smart responsive-hydrogel dressings with potential clinical diabetic wound healing properties.Military Medical Research · 2023Review
- Polymeric Network Hierarchically Organized on Carbon Nano-onions: Block Polymerization as a Tool for the Controlled Formation of Specific Pore Diameters.ACS applied polymer materials · 2022Article
- Branched PCL-Based Thermogelling Copolymers: Controlling Polymer Architecture to Tune Drug Release Profiles.Frontiers in bioengineering and biotechnology · 2022Article
- 3D Printing of Macro Porous Sol-Gel Derived Bioactive Glass Scaffolds and Assessment of Biological Response.Materials (Basel, Switzerland) · 2021Article
- (Macro)molecular self-assembly for hydrogel drug delivery.Advanced drug delivery reviews · 2021Review
- PEG-Coated Large Mesoporous Silicas as Smart Platform for Protein Delivery and Their Use in a Collagen-Based Formulation for 3D Printing.International journal of molecular sciences · 2021Article
- Thermoresponsive Nanogels Based on Different Polymeric Moieties for Biomedical Applications.Gels (Basel, Switzerland) · 2020Review
- Advances in Materials for Soft Stretchable Conductors and Their Behavior under Mechanical Deformation.Polymers · 2020Review
- Synthesis and Investigation of Thermo-Induced Gelation of Partially Cross-Linked Poly-2-isopropyl-2-oxazoline in Aqueous Media.Polymers · 2020Article
- Self-Assemblable Polymer Smart-Blocks for Temperature-Induced Injectable Hydrogel in Biomedical Applications.Frontiers in chemistry · 2020Review
- The Rediscovery of POSS: A Molecule Rather than a Filler.Polymers · 2018Article
- Biocompatible and Antibacterial Nitric Oxide-Releasing Pluronic F-127/Chitosan Hydrogel for Topical Applications.Polymers · 2018Article
- Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Pluronic F127 exhibits thermogelling behaviour at 20⁻30 °C via a micelle packing mechanism. Disruption of the micelle packing increases the sol-gel temperature, but results in the decrease of modulus. Herein, we reported a method to modify F127 with polyhedral oligosilsesquioxane (POSS) to impart a higher gelling temperature without yielding the property and strength of the thermogel. The thermal degradation temperature was enhanced to 15 °C after POSS incorporation and the gelling temperature shifted 10 °C higher, without sacrificing the modulus of the gel. Rheological studies supported the claim that the gel property was reinforced after POSS incorporation. F127-POSS copolymer matrix stored more energy from POSS reinforcement, which saw larger Lissajous curve areas before the collapse of the microstructure for the same amount of stress applied. These results indicated that modification with POSS would raise the sol-gel transition temperature without sacrificing the modulus of the gel.
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Registered trials
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