ArticleAngewandte Chemie (International ed. in English)2019
Unprecedented Five-Coordinate Iron(IV) Imides Generate Divergent Spin States Based on the Imide R-Groups.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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21 citing papers in PubMed.
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- Ligand engineering of tetra N-heterocyclic carbenes for boosting catalytic aziridination.Dalton transactions (Cambridge, England : 2003) · 2024Article
- A Mechanistic Study on Iron-Based Styrene Aziridination: Understanding Epoxidation via Nitrene Hydrolysis.Molecules (Basel, Switzerland) · 2024Article
- Poly(imidazolyliden-yl)borato Complexes of Tungsten: Mapping Steric vs. Electronic Features ofMolecules (Basel, Switzerland) · 2023Article
- Spin polarization assisted facile C-H activation by anChemical science · 2023Article
- Discovery of a simple iron catalyst reveals the intimate steps of C-H amination to form C-N bonds.Chemical science · 2023Article
- Cost-Effective HAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes.Angewandte Chemie (International ed. in English) · 2022Article
- Stabilization of a high-spin three-coordinate Fe(iii) imidyl complex by radical delocalization.Chemical science · 2022Article
- Between imide, imidyl and nitrene - an imido iron complex in two oxidation states.Chemical science · 2022Article
- Reversible C-C Bond Cleavage of a Cobalt Diketimide into an Elusive Cobalt Aryl Nitrenoid Complex.Angewandte Chemie (International ed. in English) · 2022Article
- A Pair of Cobalt(III/IV) Terminal Imido Complexes.Angewandte Chemie (International ed. in English) · 2021Article
- Actinide tetra-N-heterocyclic carbene 'sandwiches'.Chemical science · 2021Article
- Activation of Molecular Oxygen by a Cobalt(II) Tetra-NHC Complex*.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- A Stable Homoleptic Organometallic Iron(IV) Complex.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- A Chiral Macrocyclic Tetra-N-Heterocyclic Carbene Yields an "All Carbene" Iron Alkylidene Complex.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Direct Manipulation of Metal Imido Geometry: Key Principles to Enhance C-H Amination Efficacy.Journal of the American Chemical Society · 2019Article
- A μ-Phosphido Diiron Dumbbell in Multiple Oxidation States.Angewandte Chemie (International ed. in English) · 2019Review
- One macrocyclic ligand, four oxidation states: A 16-atom ringed dianionic tetra-NHC macrocycle and its Cr(II) through Cr(V) complexes.Organometallics · 2019Article
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Abstract
Three five-coordinate iron(IV) imide complexes have been synthesized and characterized. These novel structures have disparate spin states on the iron as a function of the R-group attached to the imide, with alkyl groups leading to low-spin diamagnetic (S=0) complexes and an aryl group leading to an intermediate-spin (S=1) complex. The different spin states lead to significant differences in the bonding about the iron center as well as the spectroscopic properties of these complexes. Mössbauer spectroscopy confirmed that all three imide complexes are in the iron(IV) oxidation state. The combination of diamagnetism and
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