Evidence map›Paper›PMID 30971087›Full record

ArticleJournal of the American Chemical Society2019

Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis.

Caleb Karmel, Zhewei Chen, John F Hartwig

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
5.9field-weighted citation impact, top 3% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed, 81 citations in OpenAlex.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Review
  10. Aluminium-Catalyzed C(sp)-H Borylation of Alkynes.Angewandte Chemie (International ed. in English) · 2021
    Article
  11. Article
  12. Article
  13. meta-Selective C-H Arylation of Fluoroarenes and Simple Arenes.Angewandte Chemie (International ed. in English) · 2020
    Article
  14. Article
  15. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds.Journal of the American Chemical Society · 2020
    Article
  16. Article
  17. Article
  18. Article
  19. Copper-Mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 1 institution in 1 country.

Caleb KarmelDepartment of Chemistry , University of California , Berkeley , California 94720 , United States.
Zhewei ChenDepartment of Chemistry , University of California , Berkeley , California 94720 , United States.
John F HartwigDepartment of Chemistry , University of California , Berkeley , California 94720 , United States.ORCID 0000-0002-4157-468X
University of California, Berkeley · US

Funding

Discovery and Development of Organic Reactions Catalyzed by Transition Metals Valuable for Medicinal ChemistryR35GM130387 · NIGMS · UNIVERSITY OF CALIFORNIA BERKELEY · PI John F Hartwig · 2019 to 2026
$7.1M
Catalytic Functionalization of C-H Bonds with Main Group ReagentsR01GM115812 · NIGMS · UNIVERSITY OF CALIFORNIA BERKELEY · PI HARTWIG, JOHN F · 2015 to 2018
$1.3M
NIGMS NIH HHS R01 GM115812NIGMS NIH HHS R35 GM130387
6 · The paper itself

Abstract

We report a new system for the silylation of aryl C-H bonds. The combination of [Ir(cod)(OMe)]

Indexed as

Benzene DerivativesCatalysisCoordination ComplexesDeuteriumIridiumKineticsLigandsModels, ChemicalOrganosilicon CompoundsPhenanthrolinesBenzene DerivativesCoordination ComplexesDeuteriumIridiumLigandsOrganosilicon CompoundsPhenanthrolines

Identifiers

PMID30971087
PMCPMC6839914
OpenAlexW2939623643

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.