ArticleJournal of the American Chemical Society2019
Taming the Complexity of Donor-Acceptor Stenhouse Adducts: Infrared Motion Pictures of the Complete Switching Pathway.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
22 citing papers in PubMed.
- Programming photoactuation by modulating the degree of charge-separation in DASA-based liquid crystal elastomers.Chemical science · 2026Article
- Fluorescence resonance energy transfer between isomers of molecular photoswitches.Nature communications · 2026Article
- Multistate photoswitches beyond on and off.Nature communications · 2026Review
- Reversible Photoswitching of Donor-Acceptor Stenhouse Adducts in Water.Journal of the American Chemical Society · 2026Article
- The Effect of Aldehyde and Carboxylic Acid Substitution on the Isomerization of Hemithioindigo Photoswitches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Excited-State Dynamics and Electron-Withdrawing Group Effects in Two-Photon Switchable Donor-Acceptor Stenhouse Adducts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Hemiphosphoindigos as a platform for chiroptical or water soluble photoswitching.Nature communications · 2025Article
- Compartmentalizing Donor-Acceptor Stenhouse Adducts for Structure-Property Relationship Analysis.Journal of the American Chemical Society · 2025Review
- Visible light-responsive materials: the (photo)chemistry and applications of donor-acceptor Stenhouse adducts in polymer science.Chemical Society reviews · 2023Review
- Tethered together: DASA design towards aqueous compatibility.Chemical science · 2023Article
- Controlling Isomerization of Photoswitches to Modulate 2D Logic-in-Memory Devices by Organic-Inorganic Interfacial Strategy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Donor-acceptor Stenhouse adduct functionalised polymer microspheres.Polymer chemistry · 2023Article
- Harnessing molecular isomerization in polymer gels for sequential logic encryption and anticounterfeiting.Science advances · 2022Article
- A multi-stage single photochrome system for controlled photoswitching responses.Nature chemistry · 2022Article
- Time-resolved infrared absorption spectroscopy applied to photoinduced reactions: how and why.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2022Review
- Hemithioindigo-Based Trioxobicyclononadiene: 3D Multiswitching of Electronic and Geometric Properties.Journal of the American Chemical Society · 2022Article
- Molecular photoswitches in aqueous environments.Chemical Society reviews · 2021Review
- All-Red-Light Photoswitching of Indirubin Controlled by Supramolecular Interactions.Journal of the American Chemical Society · 2021Article
- Promoting the Furan Ring-Opening Reaction to Access New Donor-Acceptor Stenhouse Adducts with Hexafluoroisopropanol.Angewandte Chemie (International ed. in English) · 2021Article
- Redesigning donor-acceptor Stenhouse adduct photoswitches through a joint experimental and computational study.Chemical science · 2021Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Switches that can be actively steered by external stimuli along multiple pathways at the molecular level are the basis for next-generation responsive material systems. The operation of commonly employed molecular photoswitches revolves around one key structural coordinate. Photoswitches with functionalities that depend on and can be addressed along multiple coordinates would offer novel means to tailor and control their behavior and performance. The recently developed donor-acceptor Stenhouse adducts (DASAs) are versatile switches suitable for such applications. Their photochemistry is well understood, but is only responsible for part of their overall photoswitching mechanism. The remaining thermal switching pathways are to date unknown. Here, rapid-scan infrared absorption spectroscopy is used to obtain transient fingerprints of reactions occurring on the ground state potential energy surface after reaching structures generated through light absorption. The spectroscopic data are interpreted in terms of structural transformations using kinetic modeling and quantum chemical calculations. Through this combined experimental-theoretical approach, we are able to unravel the complexity of the multidimensional ground-state potential energy surface explored by the photoswitch and use this knowledge to predict, and subsequently confirm, how DASA switches can be guided along this potential energy surface. These results break new ground for developing user-geared DASA switches but also shed light on the development of novel photoswitches in general.
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