Evidence map›Paper›PMID 30966269›Full record

ArticlePolymers2018

Optimization of Temperature Sensing with Polymer-Embedded Luminescent Ru(II) Complexes.

Nelia Bustamante, Guido Ielasi, Maximino Bedoya, Guillermo Orellana

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
2.4field-weighted citation impact, top 14% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 32 citations in OpenAlex.

  1. Article
  2. Article
  3. Luminescence Thermometry with Nanoparticles: A Review.Nanomaterials (Basel, Switzerland) · 2023
    Review
  4. Article
  5. Article
  6. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Nelia BustamanteChemical Optosensors and Applied Photochemistry Group (GSOLFA), Department of Organic Chemistry, Faculty of Chemistry, Universidad Complutense de Madrid, E-28040 Madrid, Spain. nbustamante@aenor.es.
Guido IelasiChemical Optosensors and Applied Photochemistry Group (GSOLFA), Department of Organic Chemistry, Faculty of Chemistry, Universidad Complutense de Madrid, E-28040 Madrid, Spain. gielasi@ucm.es.
Maximino BedoyaChemical Optosensors and Applied Photochemistry Group (GSOLFA), Department of Organic Chemistry, Faculty of Chemistry, Universidad Complutense de Madrid, E-28040 Madrid, Spain. mabedoya@ucm.es.
Guillermo OrellanaChemical Optosensors and Applied Photochemistry Group (GSOLFA), Department of Organic Chemistry, Faculty of Chemistry, Universidad Complutense de Madrid, E-28040 Madrid, Spain. orellana@quim.ucm.es.ORCID 0000-0002-4572-6564
Universidad Complutense de Madrid · ES

Funding

EU International Training Networks FP7-PEOPLE-2013-ITN, ID 607590 "SAMOSS"European Regional Development Fund CTQ2015-69278-C2-2-RMinisterio de Economía y Competitividad CTQ2015-69278-C2-2-R
6 · The paper itself

Abstract

Temperature is a key parameter in many fields and luminescence-based temperature sensing is a solution for those applications in which traditional (mechanical, electrical, or IR-based) thermometers struggle. Amongst the indicator dyes for luminescence thermometry, Ru(II) polyazaheteroaromatic complexes are an appealing option to profit from the widespread commercial technologies for oxygen optosensing based on them. Six ruthenium dyes have been studied, engineering their structure for both photostability and highest temperature sensitivity of their luminescence. The most apt Ru(II) complex turned out to be bis(1,10-phenanthroline)(4-chloro-1,10-phenanthroline)ruthenium(II), due to the combination of two strong-field chelating ligands (phen) and a substituent with electron withdrawing effect on a conjugated position of the third ligand (4-Clphen). In order to produce functional sensors, the dye has been best embedded into poly(ethyl cyanoacrylate), due to its low permeability to O₂, high temperature sensitivity of the indicator dye incorporated into this polymer, ease of fabrication, and excellent optical quality. Thermosensitive elements have been fabricated thereof as optical fiber tips for macroscopic applications (water courses monitoring) and thin spots for microscopic uses (temperature measurements in cell culture-on-a-chip). With such dye/polymer combination, temperature sensing based on luminescence lifetime measurements allows 0.05 °C resolution with linear response in the range of interest (0⁻40 °C).

Indexed as

luminescence lifetimeluminescent sensorsoptical fiberpoly(ethyl cyanoacrylate)Ru(II) dyestemperaturewater monitoring

Identifiers

PMID30966269
PMCPMC6414956
OpenAlexW2790416223

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.