ArticlePolymers2017
Surfactant-Free RAFT Emulsion Polymerization of Styrene Using Thermoresponsive macroRAFT Agents: Towards Smart Well-Defined Block Copolymers with High Molecular Weights.
Article in Polymers, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- RAFT Emulsion Polymerization of Styrene Using a Poly((Polymers · 2021Article
- Synthesis of Poly(methacrylic acid)-Polymers · 2021Article
- Experimental Design in Polymer Chemistry-A Guide towards True Optimization of a RAFT Polymerization Using Design of Experiments (DoE).Polymers · 2021Article
- Trends inPolymers · 2019Article
- Synthesis of Poly(3-vinylpyridine)-Materials (Basel, Switzerland) · 2019Article
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2 authors.
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Abstract
The combination of reversible addition⁻fragmentation chain transfer (RAFT) and emulsion polymerization has recently attracted much attention as a synthetic tool for high-molecular-weight block copolymers and their micellar nano-objects. Up to recently, though, the use of thermoresponsive polymers as both macroRAFT agents and latex stabilizers was impossible in aqueous media due to their hydrophobicity at the usually high polymerization temperatures. In this work, we present a straightforward surfactant-free RAFT emulsion polymerization to obtain thermoresponsive styrenic block copolymers with molecular weights of around 100 kDa and their well-defined latexes. The stability of the aqueous latexes is achieved by adding 20 vol % of the cosolvent 1,4-dioxane (DOX), increasing the phase transition temperature (PTT) of the used thermoresponsive poly(
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