Microstructure and Performance of a Porous Polymer Membrane with a Copper Nano-Layer Using Vapor-Induced Phase Separation Combined with Magnetron Sputtering.

Antibacterial metalized poly(vinylidene fluoride) (PVDF) porous membranes with a nano-layer were obtained via the method of vapor-induced phase separation combined with magnetron sputtering of copper. Magnetron sputtering has such advantages as high deposition rates, low substrate temperatures, and good adhesion of films on substrates. The influence brought by deposition time on the microstructure, hydrophobic property, copper distribution state, anti-biofouling, and permeation separation performance was investigated via atomic force microscopy (AFM), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray (EDX) spectrometry, contact angle measurements, and capillary flow porometry, along with the porosity, water flux, protein solution flux, rejection rate, water flux recovery rate, and antibacterial property. The results showed that copper particles formed island-type deposits on the membrane surface and were embedded into cross-section pores near the surface owning to the interconnection of pores. Subsequently, the water flux and protein solution flux declined, but the rejection rate and water flux recovery rate increased. Meanwhile, Cu-coated PVDF membranes exhibited an excellent antibacterial ability.