Evidence map›Paper›PMID 30965773›Full record

ReviewPolymers2017

Precise Synthesis of Macromolecular Architectures by Novel Iterative Methodology Combining Living Anionic Polymerization with Specially Designed Linking Chemistry.

Raita Goseki, Shotaro Ito, Yuri Matsuo, Tomoya Higashihara, Akira Hirao

Abstract readReview
PubMed Full text at PMC Publisher
In one paragraph

Review in Polymers, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Review
  2. Article
  3. Review
  4. Article
  5. Trends inPolymers · 2019
    Article
  6. Article
  7. Synthesis of Poly(Polymers · 2019
    Article
  8. Anionic Polymerization Using Flow Microreactors.Molecules (Basel, Switzerland) · 2019
    Review
  9. Article
  10. Review
  11. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Raita GosekiPolymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1, Ohokayama, Meguro-ku, Tokyo 152-8552, Japan. rgoseki@polymer.titech.ac.jp.
Shotaro ItoPolymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1, Ohokayama, Meguro-ku, Tokyo 152-8552, Japan. sito@polymer.titech.ac.jp.
Yuri MatsuoPolymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1, Ohokayama, Meguro-ku, Tokyo 152-8552, Japan. ymatsuo@polymer.titech.ac.jp.
Tomoya HigashiharaDepartment of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, Yamagata 992-8510, Japan. thigashihara@yz.yamagata-u.ac.jp.
Akira HiraoPolymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1, Ohokayama, Meguro-ku, Tokyo 152-8552, Japan. ahirao@email.plala.or.jp.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This article reviews the development of a novel all-around iterative methodology combining living anionic polymerization with specially designed linking chemistry for macromolecular architecture syntheses. The methodology is designed in such a way that the same reaction site is always regenerated after the polymer chain is introduced in each reaction sequence, and this "polymer chain introduction and regeneration of the same reaction site" sequence is repeatable. Accordingly, the polymer chain can be successively and, in principle, limitlessly introduced to construct macromolecular architectures. With this iterative methodology, a variety of synthetically difficult macromolecular architectures, i.e., multicomponent μ-star polymers, high generation dendrimer-like hyperbranched polymers, exactly defined graft polymers, and multiblock polymers having more than three blocks, were successfully synthesized.

Indexed as

benzyl bromideexactly defined graft polymershigh generation dendrimer-like hyperbranched polymeriterative methodologylinking chemistryliving anionic polymerizationmultiblock polymersα-phenylacrylateμ-star polymer

Identifiers

PMID30965773
PMCPMC6418567

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.