ArticleSensors (Basel, Switzerland)2019
The Applicability of 2-amino-4,6-diphenyl-pyridine-3-carbonitrile Sensors for Monitoring Different Types of Photopolymerization Processes and Acceleration of Cationic and Free-Radical Photopolymerization Under Near UV Light.
Article in Sensors (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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9 citing papers in PubMed.
- Application of Photoactive Compounds in Cancer Theranostics: Review on Recent Trends from Photoactive Chemistry to Artificial Intelligence.Molecules (Basel, Switzerland) · 2024Review
- Synthesis, Cytotoxicity, and Photophysical Investigations of 2-Amino-4,6-diphenylnicotinonitriles: An Experimental and Theoretical Study.Molecules (Basel, Switzerland) · 2024Article
- Fluorescence-readout as a powerful macromolecular characterisation tool.Chemical science · 2023Review
- Influence of the Type of Nanofillers on the Properties of Composites Used in Dentistry and 3D Printing.International journal of molecular sciences · 2023Article
- Fluorescence Assay for the Determination of d-Panthenol Based on Novel Ring-Fused 2-Pyridone Derivative.International journal of molecular sciences · 2020Article
- A New Approach to Micromachining: High-Precision and Innovative Additive Manufacturing Solutions Based on Photopolymerization Technology.Materials (Basel, Switzerland) · 2020Review
- Double Role of Diphenylpyridine Derivatives as Fluorescent Sensors for Monitoring Photopolymerization and the Determination of the Efficiencies of the Generation of Superacids by Cationic Photoinitiators.Sensors (Basel, Switzerland) · 2020Article
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Abstract
The performance of a series of 2-amino-4,6-diphenyl-pyridine-3-carbonitrile derivatives as fluorescent molecular sensors for monitoring photopolymerization processes of different monomers by the Fluorescence Probe Technique (FPT) was studied. It has been shown that the new derivatives are characterized by much higher sensitivity than the commercially available 7-diethylamino-4-methylcoumarin (Coumarin 1) and trans-2-(2',5'-dimethoxyphenyl)ethenyl-2,3,4, 5,6-pentafluorobenzene (25ST) probes. It has been discovered that the 2-amino-4,6-diphenyl-pyridine-3-carbonitrile derivatives accelerate the cationic photopolymerization process initiated with diphenyliodonium photoinitiators at the wavelength where the photoinitiator alone does not work. They are particularly efficient for the photoinitiation of cationic photopolymerization of an epoxide and vinyl monomers. Consequently, the application of the 2-amino-4,6-diphenyl-pyridine-3-carbonitrile derivatives in a dual role: (a) as fluorescent sensors for monitoring the free-radical, thiol-ene and cationic polymerization progress, and (b) as long-wavelength co-initiators for diphenyliodonium salts initiators, is proposed.
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