ArticleNature chemistry2019
Catalytic living ring-opening metathesis polymerization with Grubbs' second- and third-generation catalysts.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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Who cites it
17 citing papers in PubMed.
- Overcoming the Reversibility in the Diels-Alder Reaction of Bio-Based Electron-Poor Furans with Maleimides Through Liquid-to-Solid Phase Transition.International journal of molecular sciences · 2025Article
- Hydrazine-Catalysed Ring-Opening Metathesis Polymerization Of Cyclobutenes.Angewandte Chemie (International ed. in English) · 2024Article
- Polymer-Metal-Organic Frameworks (polyMOFs) Based on Tailor-Made Poly(alkenamer)s.Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Bottlebrush Networks: A Primer for Advanced Architectures.Angewandte Chemie (International ed. in English) · 2024Review
- Modern Trends in Polymerization-Induced Self-Assembly.Polymers · 2024Review
- Triazole-modified Ru-carbene complexes: A valid olefin metathesis pre-catalyst for dynamic covalent chemistry via C=C bond formation.Chem catalysis · 2023Article
- Catalytic living ROMP: block copolymers from macro-chain transfer agents.Polymer chemistry · 2023Article
- Recent Advances in Drug Release, Sensing, and Cellular Uptake of Ring-Opening Metathesis Polymerization (ROMP) Derived Poly(olefins).ACS omega · 2023Review
- Article
- Chain transfer agents for the catalytic ring opening metathesis polymerization of norbornenes.Chemical science · 2022Article
- Metal-Free Ring-Opening Metathesis Polymerization with Hydrazonium Initiators.Angewandte Chemie (International ed. in English) · 2022Article
- Degradable polymers via olefin metathesis polymerization.Progress in polymer science · 2021Article
- Oxanorbornenes: promising new single addition monomers for the metathesis polymerization.Chemical science · 2021Article
- The Impact of Water on Ru-Catalyzed Olefin Metathesis: Potent Deactivating Effects Even at Low Water Concentrations.ACS catalysis · 2021Article
- Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications.Accounts of chemical research · 2020Article
- Combining enyne metathesis with long-established organic transformations: a powerful strategy for the sustainable synthesis of bioactive molecules.Beilstein journal of organic chemistry · 2020Review
- Tailored silyl ether monomers enable backbone-degradable polynorbornene-based linear, bottlebrush and star copolymers through ROMP.Nature chemistry · 2019Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In a conventional living ring-opening metathesis polymerization (ROMP), an equal number of ruthenium complexes to the number of polymer chains synthesized are required. This can lead to high loadings of ruthenium complexes when aiming for shorter polymers. Here, a reversible chain-transfer agent was used to produce living ROMP polymers from norbornene derivatives using catalytic amounts of Grubbs' ruthenium complexes. The polymers obtained by this method showed all of the characteristics of a living polymerization (that is, good molecular weight control, narrow molecular weight dispersities and the ability to form block copolymers). Monomers carrying functional moieties such as ferrocene, coumarin or a triisopropylsilyl-protected primary alcohol could also be catalytically polymerized in a living fashion. The method presented follows a degenerative chain-transfer process and is more economical and environmentally friendly compared with previous living ROMP procedures as it utilizes only catalytic amounts of costly and toxic ruthenium complexes.
Identifiers
30962611What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.