ReviewPolymers2019
Kinetics of Alkoxysilanes and Organoalkoxysilanes Polymerization: A Review.
Review in Polymers, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 73 papers.
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Who cites it
73 citing papers in PubMed.
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- Product distribution in the silicatein-catalysed synthesis of polydimethylsiloxane.Catalysis science & technology · 2026Article
- Studies on electrospun PVDF/Silanized hyperbranched polyester of Gen-1 nanofibers as Piezo and Triboelectric nanogenerators.Scientific reports · 2026Article
- Effect of the ORMOSIL Used for the Functionalization of MSNs in the Removal of Anionic Contaminants from Sugarcane Processing Wastewater.Nanomaterials (Basel, Switzerland) · 2026Article
- Synthesis, Antioxidant Activity, and Structure Analysis Relationship Study of Silyl-Alkylthioetheres from 2-Mercaptobenzimidazole.Molecules (Basel, Switzerland) · 2026Article
- Enhanced kinetic performance and stability of catalase immobilized on epoxy-functionalized kaolinite.Scientific reports · 2026Article
- Template-assisted synthesis of pH-responsive hollow mesoporous silica nanocarriers: the role of engineered pores and surface characteristics.Journal of materials science. Materials in medicine · 2026Article
- P-N Nanoporous Silicon Fabrication Using Photoelectrochemical Etching and Ultrasonic Vibration and Liquid-Phase Bonding for Optoelectronic Applications.Micromachines · 2026Article
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- Oligonucleotide surface attachment by tosylation for digital detection of microRNA using photonic resonator absorption microscopy.APL bioengineering · 2025Article
- Assessment of physicochemical properties and biological responses of chemically surface-modified microcapsules for self-healing dental restorative materials.Materials & design · 2025Article
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- Molecular Mechanisms of Silicone Network Formation: Bridging Scales from Curing Reactions to Percolation and Entanglement Analyses.Polymers · 2025Article
- Development of a Generic Bio-Interface for Immuno-Biodetection on an Oxide Surface Targeting Pathogen Bacteria.Molecules (Basel, Switzerland) · 2025Article
- The cleavage of indinavir sulfate: synthesis and characterization of a cis-1-amino-2-indanol salt.Acta crystallographica. Section C, Structural chemistry · 2025Article
- Silanes for conservation of archaeological woods using modeled birch wood: antifungal, physical-chemical and TGA studies.Scientific reports · 2025Article
13 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Scientists from various different fields use organo-trialkoxysilanes and tetraalkoxysilanes in a number of applications. The silica-based materials are sometimes synthesized without a good understanding of the underlying reaction kinetics. This literature review attempts to be a comprehensive and more technical article in which the kinetics of alkoxysilanes polymerization are discussed. The kinetics of polymerization are controlled by primary factors, such as catalysts, water/silane ratio, pH, and organo-functional groups, while secondary factors, such as temperature, solvent, ionic strength, leaving group, and silane concentration, also have an influence on the reaction rates. Experiments to find correlations between these factors and reaction rates are restricted to certain conditions and most of them disregard the properties of the solvent. In this review, polymerization kinetics are discussed in the first two sections, with the first section covering early stage reactions when the reaction medium is homogenous, and the second section covering when phase separation occurs and the reaction medium becomes heterogeneous. Nuclear magnetic resonance (NMR) spectroscopy and other techniques are discussed in the third section. The last section summarizes the study of reaction mechanisms by using ab initio and Density Functional Theory (DFT) methods alone, and in combination with molecular dynamics (MD) or Monte Carlo (MC) methods.
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