ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
Cobalt-Catalyzed Aqueous Dehydrogenation of Formic Acid.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Hydrogen production from formic acid catalyzed by NHC-Cu complexes.Beilstein journal of organic chemistry · 2026Article
- A Homobimetallic Frustrated Lewis Pair Cobalt Catalyst for the Methanolysis of Hydrosilanes.Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Mechanistic Investigation into Copper(I) Hydride Catalyzed Formic Acid Dehydrogenation.ACS catalysis · 2024Article
- Formic acid stability in different solvents by DFT calculations.Journal of molecular modeling · 2024Article
- Transition metal pincer catalysts for formic acid dehydrogenation: a mechanistic perspective.Frontiers in chemistry · 2024Review
- Efficient [Fe-Imidazole@SiONanomaterials (Basel, Switzerland) · 2023Article
- Sterically and Electronically Flexible Pyridylidene Amine Dinitrogen Ligands at Palladium: Hemilabile cis/trans Coordination and Application in Dehydrogenation Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Base-Free Catalytic Hydrogen Production from Formic Acid Mediated by a Cubane-Type MoInorganic chemistry · 2022Article
- Amine-Functionalized Natural Halloysite Nanotubes Supported Metallic (Pd, Au, Ag) Nanoparticles and Their Catalytic Performance for Dehydrogenation of Formic Acid.Nanomaterials (Basel, Switzerland) · 2022Article
- Recent Progress in Homogeneous Catalytic Dehydrogenation of Formic Acid.Molecules (Basel, Switzerland) · 2022Review
- HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes.Chemical science · 2021Article
- Cobalt-Catalyzed Aqueous Dehydrogenation of Formic Acid.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
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Authors and funding
7 authors.
Funding
Abstract
Among the known liquid organic hydrogen carriers, formic acid attracts increasing interest in the context of safe and reversible storage of hydrogen. Here, the first molecularly defined cobalt pincer complex is disclosed for the dehydrogenation of formic acid in aqueous medium under mild conditions. Crucial for catalytic activity is the use of the specific complex 3. Compared to related ruthenium and manganese complexes 7 and 8, this optimal cobalt complex showed improved performance. DFT computations support an innocent non-classical bifunctional outer-sphere mechanism on the triplet state potential energy surface.
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