ArticlePhilosophical transactions. Series A, Mathematical, physical, and engineering sciences2019
Chemical interactions and dynamics with femtosecond X-ray spectroscopy and the role of X-ray free-electron lasers.
Article in Philosophical transactions. Series A, Mathematical, physical, and engineering sciences, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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17 citing papers in PubMed, 51 citations in OpenAlex.
- Pursuing Heteroleptic Ligand Design Principles for Photoactive Fe Complexes with Ultrafast X-ray Emission and Variable-Temperature Optical Spectroscopies.Journal of the American Chemical Society · 2026Article
- Photochemistry of Aromatic N-Oxides in Water Probed by Time-Resolved X-ray Absorption Spectroscopy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Diffractive wavefront correction for Fe L-edge spectroscopy on the meV scale.Journal of synchrotron radiation · 2026Article
- Excited-State Identification of a Nickel-Bipyridine Photocatalyst by Time-Resolved X-ray Absorption Spectroscopy.The journal of physical chemistry letters · 2024Article
- In situ X-ray spectroscopies beyond conventional X-ray absorption spectroscopy on deciphering dynamic configuration of electrocatalysts.Nature communications · 2023Review
- Revealing core-valence interactions in solution with femtosecond X-ray pump X-ray probe spectroscopy.Nature communications · 2023Article
- Element- and enantiomer-selective visualization of molecular motion in real-time.Nature communications · 2023Article
- Development of an experimental apparatus to observe ultrafast phenomena by tender X-ray absorption spectroscopy at PAL-XFEL.Journal of synchrotron radiation · 2022Article
- Using X-ray free-electron lasers for spectroscopy of molecular catalysts and metalloenzymes.Nature reviews. Physics · 2021Article
- XABOOM: An X-ray Absorption Benchmark of Organic Molecules Based on Carbon, Nitrogen, and Oxygen 1s → π* Transitions.Journal of chemical theory and computation · 2021Article
- An assessment of different electronic structure approaches for modeling time-resolved x-ray absorption spectroscopy.Structural dynamics (Melville, N.Y.) · 2021Article
- Ultrafast structural dynamics of in-cage isomerization of diiodomethane in solution.Chemical science · 2020Article
- Visualizing ultrafast chemical dynamics with X-rays.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- XANES Measurements for Studies of Adsorbed Protein Layers at Liquid Interfaces.Materials (Basel, Switzerland) · 2020Article
- The future iron age.Nature chemistry · 2020Article
- Vibronic coherence evolution in multidimensional ultrafast photochemical processes.Nature communications · 2019Article
- The measurement of ultrafast electronic and structural dynamics with X-rays.Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2019Article
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1 author at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
X-ray free-electron lasers with intense, tuneable and short-pulse X-ray radiation are transformative tools for the investigation of transition-metal complexes and metalloproteins. This becomes apparent in particular when combining the experimental observables from X-ray spectroscopy with modern theoretical tools for calculations of electronic structures and X-ray spectra from first principles. The combination gives new insights into how charge and spin densities change in chemical reactions and how they determine reactivity. This is demonstrated for the investigations of structural dynamics with metal K-edge absorption spectroscopy, spin states in excited-state dynamics with metal 3p-3d exchange interactions, the frontier-orbital interactions in dissociation and substitution reactions with metal-specific X-ray spectroscopy, and studies of metal oxidation states with femtosecond pulses for 'probe-before-destroy' spectroscopy. The role of X-ray free-electron lasers is addressed with thoughts about how they enable 'bringing back together' different aspects of the same problem and this is thought to go beyond a conventional review paper where these aspects are formulated in italic font type in a prequel, an interlude and in a sequel. This article is part of the theme issue 'Measurement of ultrafast electronic and structural dynamics with X-rays'.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.