ArticleDalton transactions (Cambridge, England : 2003)2019
Mn
Article in Dalton transactions (Cambridge, England : 2003), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed, 24 citations in OpenAlex.
- Mn(III)-O-Ce(IV) as a Surrogate for Highly Reactive Non-Heme Mn(IV)═O Species Supported by Benzimidazole-Based Ligand.Inorganic chemistry · 2026Article
- Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(IV)-oxo adducts.Dalton transactions (Cambridge, England : 2003) · 2021Article
- Concerted proton-electron transfer reactions of manganese-hydroxo and manganese-oxo complexes.Chemical communications (Cambridge, England) · 2020Article
- Iron and manganese oxo complexes, oxo wall and beyond.Nature reviews. Chemistry · 2020Review
- Structural Characterization of a Series of N5-Ligated MnChemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies.Inorganic chemistry · 2019Article
- Steric control of dioxygen activation pathways for MnDalton transactions (Cambridge, England : 2003) · 2019Article
Corrections and comments
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Authors and funding
8 authors at 2 institutions in 2 countries.
Funding
Abstract
Using the pentadentate ligand (N-bis(1-methyl-2-benzimidazolyl)methyl-N-(bis-2-pyridylmethyl)amine, 2pyN2B), presenting two pyridyl and two (N-methyl)benzimidazolyl donor moieties in addition to a central tertiary amine, new MnII and MnIV-oxo complexes were generated and characterized. The [MnIV(O)(2pyN2B)]2+ complex showed spectroscopic signatures (i.e., electronic absorption band maxima and intensities, EPR signals, and Mn K-edge X-ray absorption edge and near-edge data) similar to those observed for other MnIV-oxo complexes with neutral, pentadentate N5 supporting ligands. The near-IR electronic absorption band maximum of [MnIV(O)(2pyN2B)]2+, as well as DFT-computed metric parameters, are consistent with the equatorial (N-methyl)benzimidazolyl ligands being stronger donors to the MnIV center than the pyridyl and quinolinyl ligands found in analogous MnIV-oxo complexes. The hydrogen- and oxygen-atom transfer reactivities of [MnIV(O)(2pyN2B)]2+ were assessed through reactions with hydrocarbons and thioanisole, respectively. When compared with related MnIV-oxo adducts, [MnIV(O)(2pyN2B)]2+ showed muted reactivity in hydrogen-atom transfer reactions with hydrocarbons. This result stands in contrast to observations for the analogous FeIV-oxo complexes, where [FeIV(O)(2pyN2B)]2+ was found to be one of the more reactive members of its class.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.