ArticleChem2018
Gold-Catalyzed Oxidative Coupling of Alkynes toward the Synthesis of Cyclic Conjugated Diynes.
Article in Chem, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Gold Redox Catalysis Enabled by Cyclic Diacyl Peroxides for Homocoupling and Cross-Coupling of Terminal Alkynes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Bidentate N-ligand-assisted gold redox catalysis with hydrogen peroxide.Nature chemistry · 2025Article
- Gold-Catalyzed Amine Cascade Addition to Diyne-Ene: Enantioselective Synthesis of 1,2-Dihydropyridines.Angewandte Chemie (International ed. in English) · 2023Article
- C-C Cross-Couplings from a Cyclometalated Au(III) CChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Homogeneous Gold-Catalyzed Oxidation Reactions.Chemical reviews · 2021Review
- Alkyne Trifunctionalization via Divergent Gold Catalysis: Combining π-Acid Activation, Vinyl-Gold Addition, and Redox Catalysis.Journal of the American Chemical Society · 2021Article
- Electrochemical gold redox catalysis for selective oxidative arylation.Green synthesis and catalysis · 2021Article
- Intermolecular Alkene Difunctionalization via Gold-Catalyzed Oxyarylation.Angewandte Chemie (International ed. in English) · 2020Article
- Facilitating Ir-Catalyzed C-H Alkynylation with Electrochemistry: Anodic Oxidation-Induced Reductive Elimination.ACS catalysis · 2020Article
- Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond.Trends in chemistry · 2020Article
- Hexafluoroisopropanol-Promoted Disulfidation and Diselenation of Alkyne, Alkene, and Allene.Organic letters · 2020Article
- Regioselective Crossed Aldol Reactions under Mild Conditions via Synergistic Gold-Iron Catalysis.Chem · 2020Article
- Diazo Activation with Diazonium Salts: Synthesis of Indazole and 1,2,4-Triazole.Organic letters · 2020Article
- Facilitating Gold Redox Catalysis with Electrochemistry: An Efficient Chemical-Oxidant-Free Approach.Angewandte Chemie (International ed. in English) · 2019Article
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Authors and funding
6 authors.
Funding
Abstract
A gold-catalyzed oxidative coupling of alkynes was developed as an efficient approach for the synthesis of challenging cyclic conjugated diynes (CCD). Compared to the classical copper-promoted oxidative coupling reaction of alkynes, this gold-catalyzed process exhibits a faster reaction rate due to the rapid reductive elimination from the Au(III) intermediate. This unique reactivity thus allowed a challenging diyne macrocyclization to take place in high efficiency. Condition screening revealed a [(
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