ArticleNature communications2019
A green metal-free fused-ring initiating substance.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
16 citing papers in PubMed.
- Article
- Isomerism as a Design Tool: Tuning the Energy-Safety Balance of a Fused Pyrazolo-Triazine N-Oxide Energetic Material.Molecules (Basel, Switzerland) · 2026Article
- Potassium-Ion-Directed Three-Dimensional Assembly of a Dense and Thermally Robust Nitrogen-Rich Tetrazine Framework.Chemistry, an Asian journal · 2026Article
- DFT study on gem-diazidocarbonimidoyl (-NCN6): Azido-cyclization mechanism, solvent effects, and high-nitrogen energetic performance.Journal of molecular modeling · 2026Article
- Synthesis and structural characterization of theRSC advances · 2026Article
- Article
- A Water-Based and Continuous-Flow-Usable Cascade: Sustainable Synthesis of Tetrazolo-Fused Heterocycles.JACS Au · 2025Article
- Crystal structure and Hirshfeld surface analysis of 5-(3-nitro-1Acta crystallographica. Section E, Crystallographic communications · 2025Article
- Introducing Azide into Fully Nitrated Systems: Charge Mutations toward Advanced Initiators.JACS Au · 2025Article
- Highly Promising Primary Explosive: A Metal-Free, Fluoro-Substituted Azo-Triazole with Unmatched Safety and Performance.JACS Au · 2025Article
- Fused Triazole-Tetrazine Assembled with Different Functional Moieties: Construction of Multipurpose Energetic Materials.ACS omega · 2024Article
- A promising perovskite primary explosive.Nature communications · 2023Article
- A series ofRSC advances · 2022Article
- Full-nitro-nitroamino cooperative action: Climbing the energy peak of benzenes with enhanced chemical stability.Science advances · 2022Article
- 2-(1,2,4-triazole-5-yl)-1,3,4-oxadiazole as a novel building block for energetic materials.Frontiers in chemistry · 2022Article
- Refinement of Copper(II) Azide with 1-Alkyl-5H-tetrazoles: Adaptable Energetic Complexes.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Over the past century, the search for lead-free, environmentally friendly initiating substances has been a highly challenging task in the field of energetic materials. Here, an organic primary explosive featuring a fused-ring structure, 6-nitro-7-azido-pyrazol[3,4-d][1,2,3]triazine-2-oxide, was designed and synthesized through a facile two-step reaction from commercially available reagents. This organic initiating substance meets nearly all of the stringent criteria of environmentally friendly primary explosives for commercial applications: it is free of toxic metals and perchlorate, has a high density, high priming ability, unusual sensitivities towards non-explosive stimuli, excellent environmental resistance, decent thermal stability, high detonation performance, satisfactory flowability and pressure durability, and is low-cost and easy to scale-up. These combined properties and performance measures surpass the current and widely used organic primary explosive, DDNP. The fused-ring organic primary explosive reported herein may find real-world application as an initiating explosive device in the near future.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.