Evidence map›Paper›PMID 30894535›Full record

ArticleNature communications2019

Axial shielding of Pd(II) complexes enables perfect stereoretention in Suzuki-Miyaura cross-coupling of Csp

Jonathan W Lehmann, Ian T Crouch, Daniel J Blair, Melanie Trobe, Pulin Wang, Junqi Li, Martin D Burke

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.

0numbers the graph read from it
0cells of the map it votes in
18citing papers in PubMed
2.8field-weighted citation impact, top 10% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

18 citing papers in PubMed, 48 citations in OpenAlex.

  1. Article
  2. Review
  3. Article
  4. Automated Iterative N─C and C─C Bond Formation.Angewandte Chemie (International ed. in English) · 2025
    Article
  5. Iridium-Catalyzed Stereocontrolled C(spJournal of the American Chemical Society · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Simultaneous Stereoinvertive and Stereoselective C(spJournal of the American Chemical Society · 2024
    Article
  10. Article
  11. Article
  12. Article
  13. Sterically Controlled Late-Stage Functionalization of Bulky Phosphines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  14. Copper-Catalyzed Stereospecific Transformations of Alkylboronic Esters.Journal of the American Chemical Society · 2022
    Article
  15. Article
  16. Article
  17. Article
  18. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 1 institution in 1 country.

Jonathan W LehmannDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA.
Ian T CrouchDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA.
Daniel J BlairDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA.ORCID http://orcid.org/0000-0002-2279-7538
Melanie TrobeDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA.
Pulin WangDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA.
Junqi LiDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA.
Martin D BurkeDepartment of Chemistry, University of Illinois at Urbana-Champaign, 454 Roger Adams Laboratory, 600S Mathews Avenue, Urbana, 61801, IL, USA. mdburke@illinois.edu.
University of Illinois Urbana-Champaign · US

Funding

Molecular Prosthetics and Lego ChemistryR35GM118185 · NIGMS · UNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN · PI Martin D Burke · 2016 to 2026
$6.6M
NIGMS NIH HHS R35 GM118185NIH HHS GM118185
6 · The paper itself

Abstract

Stereocontrolled Csp

Indexed as

Chemistry Techniques, SyntheticBoronic AcidsCatalysisFatty Acids, MonounsaturatedHumansLigandsMolecular StructurePalladiumStereoisomerism2,4,6-trimethyl-2-octenoic acidBoronic AcidsFatty Acids, MonounsaturatedLigandsPalladium

Identifiers

PMID30894535
PMCPMC6427018
OpenAlexW2924610417

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.