ArticleNature materials2019
Unified picture of anionic redox in Li/Na-ion batteries.
Article in Nature materials, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 55 papers.
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Who cites it
55 citing papers in PubMed, 493 citations in OpenAlex.
- Stereochemical origin of potential hysteresis in lithium metal batteries with lithium-rich cation-disordered rocksalt positive electrodes.Nature nanotechnology · 2026Article
- Kinetic Regulation of Anionic Redox Reaction Voltage by Metastable Over-Lithiated Surface Shells Formation for High-Energy-Density Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Enhancing the longevity of lithium-manganese-rich layered oxides by promoting oxygen redox reversibility.Nature communications · 2026Article
- Covalency stabilizes high energy vanadium oxide positive electrode for sustainable aqueous zinc-ion batteries.Nature communications · 2026Article
- Constructing high-capacity and ultra-stable biphasic layered cathodes via reductive coupling mechanism for sodium-ion batteries.Fundamental research · 2026Article
- Approaching Zero Voltage Attenuation of Lithium-Rich Cathodes through Electrochemical Relaxation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Activation of anionic redox reactions with vacancies in layered potassium manganese oxide.Fundamental research · 2026Article
- Unlocking Energy Potential: Exploiting Anionic Redox Activity in Na-Based Layered Oxides.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Substitution and electrochemistry in layered oxide cathode materials for sodium-ion batteries.Nature reviews. Chemistry · 2026Review
- Recovery of High-Voltage Oxygen Redox Activity by Eliminating Residual Oxygen Dimers.Journal of the American Chemical Society · 2025Article
- An amorphous Li-V-O-F cathode with tetrahedral coordination and O-O formal redox at low voltage.Nature materials · 2025Article
- Enhanced Anionic Redox Reaction of Na-Layered Li-Containing Mn-Based Cathodes by Cu-Mediated Reductive Coupling Mechanism.Nanomaterials (Basel, Switzerland) · 2025Article
- Clarifying the origin of molecular ONature materials · 2025Article
- Electronic band structure engineering of π-d conjugated metal-organic framework for sodium organic batteries.Nature communications · 2025Article
- The Effect of K-Doping on Activation in Co-Free Li-Rich Cathodes.Chemistry, an Asian journal · 2025Article
- Unprecedented Ultraviolet Circularly Polarized Light-Dependent Anomalous Photovoltaics in Chiral Hybrid Perovskites.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Metal-to-metal charge transfer for stabilizing high-voltage redox in lithium-rich layered oxide cathodes.Science advances · 2025Article
- Substantial oxygen loss and chemical expansion in lithium-rich layered oxides at moderate delithiation.Nature materials · 2025Article
- Visualization of Tetrahedral Li in the Alkali Layers of Li-Rich Layered Metal Oxides.Journal of the American Chemical Society · 2024Article
- Manipulating disorder within cathodes of alkali-ion batteries.Nature reviews. Chemistry · 2024Review
Corrections and comments
- Erratum issued
Authors and funding
4 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Anionic redox in Li-rich and Na-rich transition metal oxides (A-rich-TMOs) has emerged as a new paradigm to increase the energy density of rechargeable batteries. Ever since, numerous electrodes delivering extra anionic capacity beyond the theoretical cationic capacity have been reported. Unfortunately, most often the anionic capacity achieved in charge is partly irreversible in discharge. A unified picture of anionic redox in A-rich-TMOs is designed here to identify the electronic origin of this irreversibility and to propose new directions to improve the cycling performance of the electrodes. The electron localization function is introduced as a holistic tool to unambiguously locate the oxygen lone pairs in the structure and follow their participation in the redox activity of A-rich-TMOs. The charge-transfer gap of transition metal oxides is proposed as the pertinent observable to quantify the amount of extra capacity achievable in charge and its reversibility in discharge, irrespective of the material chemical composition. From this generalized approach, we conclude that the reversibility of the anionic capacity is limited to a critical number of O holes per oxygen, h
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.