ArticleScience advances2019
Enantioselective fragmentation of an achiral molecule in a strong laser field.
Article in Science advances, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
6 citing papers in PubMed.
- Exploiting correlations in multi-coincidence Coulomb explosion patterns for differentiating molecular structures using machine learning.Nature communications · 2025Article
- Spin-related excited-state phenomena in photochemistry.National science review · 2024Article
- Carrier envelope phase sensitivity of photoelectron circular dichroism.Physical chemistry chemical physics : PCCP · 2023Article
- Conformations of Steroid Hormones: Infrared and Vibrational Circular Dichroism Spectroscopy.Molecules (Basel, Switzerland) · 2023Article
- Pump-probe spectroscopy of chiral vibrational dynamics.Science advances · 2022Article
- Assessing the performance of rotational spectroscopy in chiral analysis.Chemical science · 2020Review
Corrections and comments
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chirality is omnipresent in living nature. On the single molecule level, the response of a chiral species to a chiral probe depends on their respective handedness. A prominent example is the difference in the interaction of a chiral molecule with left or right circularly polarized light. In the present study, we show by Coulomb explosion imaging that circularly polarized light can also induce a chiral fragmentation of a planar and thus achiral molecule. The observed enantiomer strongly depends on the orientation of the molecule with respect to the light propagation direction and the helicity of the ionizing light. This finding might trigger new approaches to improve laser-driven enantioselective chemical synthesis.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.