Evidence map›Paper›PMID 30860832›Full record

ArticleJournal of the American Chemical Society2019

Tuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands.

Melanie A Ehudin, Leland B Gee, Sinan Sabuncu, Augustin Braun, Pierre Moënne-Loccoz, Britt Hedman, Keith O Hodgson, Edward I Solomon, Kenneth D Karlin

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.

0numbers the graph read from it
0cells of the map it votes in
27citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

27 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Experimental electronic structures of the FeProceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Altering the Localization of an Unpaired Spin in a Formal Ni(V) Species.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024
    Article
  14. Heme-copper and Heme OJournal of inorganic biochemistry · 2023
    Review
  15. Article
  16. Highly selective synthesis of surface FeProceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  17. Article
  18. Photoexcited Ru single-atomic sites for efficient biomimetic redox catalysis.Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Melanie A EhudinDepartment of Chemistry , Johns Hopkins University , Baltimore , Maryland 21218 , United States.ORCID 0000-0002-4324-4721
Leland B GeeDepartment of Chemistry , Stanford University , Stanford , California 94305 , United States.ORCID 0000-0002-5817-3997
Sinan SabuncuDepartment of Biochemistry & Molecular Biology , Oregon Health & Science University , Portland , Oregon 97239-3098 , United States.ORCID 0000-0001-8346-8175
Augustin BraunDepartment of Chemistry , Stanford University , Stanford , California 94305 , United States.ORCID 0000-0002-9487-5769
Pierre Moënne-LoccozDepartment of Biochemistry & Molecular Biology , Oregon Health & Science University , Portland , Oregon 97239-3098 , United States.ORCID 0000-0002-7684-7617
Britt HedmanStanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory , Stanford University , Menlo Park , California 94025 , United States.
Keith O HodgsonDepartment of Chemistry , Stanford University , Stanford , California 94305 , United States.
Edward I SolomonDepartment of Chemistry , Stanford University , Stanford , California 94305 , United States.ORCID 0000-0003-0291-3199
Kenneth D KarlinDepartment of Chemistry , Johns Hopkins University , Baltimore , Maryland 21218 , United States.ORCID 0000-0002-5675-7040

Funding

X-ray Absorption Spectroscopy (XAS) pp.711-759P41GM103393 · NIGMS · STANFORD UNIVERSITY · PI HODGSON, KEITH O · 2012 to 2019
$30.6M
SPECTROSCOPIC STUDIES OF NONHEME IRON ENZYMESR01GM040392 · NIGMS · STANFORD UNIVERSITY · PI SOLOMON, EDWARD I · 1988 to 2021
$8.6M
Heme/Copper and Heme/Nonheme Iron O(2) and NO ReactivityR01GM060353 · NIGMS · JOHNS HOPKINS UNIVERSITY · PI KARLIN, KENNETH D. · 2000 to 2020
$5.9M
Nitric Oxide Reactions in MetalloenzymesR01GM074785 · NIGMS · OREGON HEALTH & SCIENCE UNIVERSITY · PI MOENNE-LOCCOZ, PIERRE · 2006 to 2019
$3.8M
Electronic Structure of Heme Enzyme Intermediates from Resonant Inelastic X-ray Scattering and L-Edge X-ray Absorption SpectroscopyF32GM122194 · NIGMS · STANFORD UNIVERSITY · PI GEE, LELAND BRUCE · 2017 to 2020
$227k
NIGMS NIH HHS F32 GM122194NIGMS NIH HHS P41 GM103393NIGMS NIH HHS R01 GM040392NIGMS NIH HHS R01 GM060353NIGMS NIH HHS R01 GM074785
6 · The paper itself

Abstract

High-valent ferryl species (e.g., (Por)Fe

Indexed as

ElectronsHemeImidazolesIronLewis AcidsLigandsModels, MolecularMolecular ConformationHemeimidazoleImidazolesIronLewis AcidsLigands

Identifiers

PMID30860832
PMCPMC6611672

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.