ArticleNature communications2019
Effects of chloride ions in acid-catalyzed biomass dehydration reactions in polar aprotic solvents.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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Who cites it
20 citing papers in PubMed, 166 citations in OpenAlex.
- Hydrogen Bond Acceptors Dramatically Promote Fructose Dehydration and Stability of Furanics Like 5-Hydroxymethylfurfural.International journal of molecular sciences · 2026Article
- Br-Mediated Pd Catalysis Promotes Intermediates Stabilization and Coupling for Anodic Electrosynthesis of Dimethyl Carbonate.Angewandte Chemie (International ed. in English) · 2026Article
- Ruthenium catalysts for hydrogenation of biomass-based levulinic acid for efficient γ-valerolactone synthesis.iScience · 2025Review
- Biphasic Production of 5-hydroxymethylfurfural (HMF) in a Recyclable Deep Eutectic Solvent-based System Catalyzed by HChemSusChem · 2025Article
- Knockout ofInternational journal of ophthalmology · 2024Article
- Engineering intraporous solvent environments: effects of aqueous-organic solvent mixtures on competition between zeolite-catalyzed epoxidation and HChemical science · 2023Article
- Intriguing Chloride: Involvement of Chloride Ions in Proton Transfers.Molecules (Basel, Switzerland) · 2022Article
- Improved Production of 5-Hydroxymethylfurfural in Acidic Deep Eutectic Solvents Using Microwave-Assisted Reactions.International journal of molecular sciences · 2022Article
- Recent Advances in the Catalytic Conversion of Biomass to Furfural in Deep Eutectic Solvents.Frontiers in chemistry · 2022Review
- Enhanced Furfural Production in Deep Eutectic Solvents Comprising Alkali Metal Halides as Additives.Molecules (Basel, Switzerland) · 2021Article
- Rhodium(i) complexes derived from tris(isopropyl)-azaphosphatrane-controlling the metal-ligand interplay.RSC advances · 2021Article
- Article
- Sulfonic Derivatives as Recyclable Acid Catalysts in the Dehydration of Fructose to 5-Hydroxymethylfurfural in Biphasic Solvent Systems.ACS omega · 2021Article
- Acid-Catalyzed Conversion of Cellulose Into Levulinic Acid With Biphasic Solvent System.Frontiers in plant science · 2021Article
- Fast predictions of liquid-phase acid-catalyzed reaction rates using molecular dynamics simulations and convolutional neural networks.Chemical science · 2020Article
- Transformation of remnant algal biomass to 5-HMF and levulinic acid: influence of a biphasic solvent system.RSC advances · 2020Article
- Mechanistic aspects of saccharide dehydration to furan derivatives for reaction media design.RSC advances · 2020Review
- Stabilization strategies in biomass depolymerization using chemical functionalization.Nature reviews. Chemistry · 2020Review
- Monosaccharides Dehydration Assisted by Formation of Borate Esters of α-Hydroxyacids in Choline Chloride-Based Low Melting Mixtures.Frontiers in chemistry · 2020Article
- Synthesis of ethanol from aryl methyl ether/lignin, COChemical science · 2019Article
Corrections and comments
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Authors and funding
12 authors at 4 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The use of polar aprotic solvents in acid-catalyzed biomass conversion reactions can lead to improved reaction rates and selectivities. We show that further increases in catalyst performance in polar aprotic solvents can be achieved through the addition of inorganic salts, specifically chlorides. Reaction kinetics studies of the Brønsted acid-catalyzed dehydration of fructose to hydroxymethylfurfural (HMF) show that the use of catalytic concentrations of chloride salts leads to a 10-fold increase in reactivity. Furthermore, increased HMF yields can be achieved using polar aprotic solvents mixed with chlorides. Ab initio molecular dynamics simulations (AIMD) show that highly localized negative charge on Cl
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.