ArticleChemical science2019
Dynamic polyimine macrobicyclic cryptands - self-sorting with component selection.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed, 78 citations in OpenAlex.
- Enabling technology for accelerated discovery of supramolecular materials.Chemical science · 2025Review
- Transfer of structural units through imine exchanges, in solution or without solvent: successive transiminations, stimuli (pH)-modulated covalent switches, and mathematical models.Frontiers in chemistry · 2025Article
- Social Self-Sorting of Quasi-Racemates: A Unique Approach for Dual-Pore Molecular Crystals.Journal of the American Chemical Society · 2024Article
- The Dynamic Chemistry of Orthoesters and Trialkoxysilanes: Making Supramolecular Hosts Adaptive, Fluxional, and Degradable.Accounts of chemical research · 2024Article
- Dynamic covalent synthesis.Chemical science · 2024Review
- Dynamic covalent self-assembly and self-sorting processes in the formation of imine-based macrocycles and macrobicyclic cages.Chemical science · 2023Article
- Porous Organic Cages.Chemical reviews · 2023Review
- Purely Covalent Molecular Cages and Containers for Guest Encapsulation.Chemical reviews · 2022Review
- Imine- and Amine-Type Macrocycles Derived from Chiral Diamines and Aromatic Dialdehydes.Molecules (Basel, Switzerland) · 2022Review
- PEEK-WC-Based Mixed Matrix Membranes Containing Polyimine Cages for Gas Separation.Molecules (Basel, Switzerland) · 2021Article
- Supramolecular Alloys from Fluorinated Hybrid TriChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Self-Sorting in Dynamic Combinatorial Libraries Leads to the Co-Existence of Foldamers and Self-Replicators.Angewandte Chemie (International ed. in English) · 2021Article
- Simultaneous Formation of a Fully Organic Triply Dynamic Combinatorial Library.Organic letters · 2021Article
- Chiral Self-sorting of Giant Cubic [8+12] Salicylimine Cage Compounds.Angewandte Chemie (International ed. in English) · 2021Article
- Endohedral Hydrogen Bonding Templates the Formation of a Highly Strained Covalent Organic Cage Compound*.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Synthetic Factors Governing Access to Tris(β-diketimine) Cyclophanes versus Tripodal Tri-β-aminoenones.The Journal of organic chemistry · 2020Article
- Examination of the Dynamic Covalent Chemistry of [2 + 3]-Imine Cages.The Journal of organic chemistry · 2020Article
- Inducing Social Self-Sorting in Organic Cages To Tune The Shape of The Internal Cavity.Angewandte Chemie (International ed. in English) · 2020Article
- Coordinative-to-covalent transformation, isomerization dynamics, and logic gate application of dithienylethene based photochromic cages.Chemical science · 2020Article
- Guest Binding Drives Host Redistribution in Libraries of CoAngewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Self-assembling macrobicyclic cryptand-type organic cages display remarkable self-sorting behavior with efficient component selection. Making use of the dynamic covalent chemistry approach, eight different cages were synthesized by condensation of tris(2-aminopropyl)amine with structurally different dialdehydes. A series of self-sorting experiments were first carried out on simple dynamic covalent libraries. They reveal the influence of different structural features of the aldehyde components on the condensation with two triamine capping units. Subsequently, self-sorting experiments were performed on more complex systems involving several dialdehyde building blocks. Altogether, the results obtained describe the effect of the presence of a heteroatom, of electrostatic interactions, of delocalization and of the flexibility/stiffness of the propensity of a component to undergo formation of a macrobicyclic cage. In the presence of a catalytic amount of acid, the macrobicyclic structure undergoes dynamic component exchange.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.