Evidence map›Paper›PMID 30842842›Full record

ArticleChemical science2019

Tuning the electronic properties of hexanuclear cobalt sulfide superatoms

Gaoxiang Liu, Andrew Pinkard, Sandra M Ciborowski, Vikas Chauhan, Zhaoguo Zhu, Alexander P Aydt, Shiv N Khanna, Xavier Roy, Kit H Bowen

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Exploration of the Electronic and Catalytic Properties of [CoNanomaterials (Basel, Switzerland) · 2026
    Article
  2. Converting COCommunications chemistry · 2023
    Article
  3. Tuning metal-metal interactions for cooperative small molecule activation.Chemical communications (Cambridge, England) · 2021
    Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Gaoxiang LiuDepartment of Chemistry , Johns Hopkins University , Baltimore , Maryland 21218 , USA . Email: kbowen@jhu.edu.ORCID 0000-0002-1001-0064
Andrew PinkardDepartment of Chemistry , Columbia University , New York , New York 10027 , USA . Email: xr2114@columbia.edu.
Sandra M CiborowskiDepartment of Chemistry , Johns Hopkins University , Baltimore , Maryland 21218 , USA . Email: kbowen@jhu.edu.ORCID 0000-0001-9453-4764
Vikas ChauhanDepartment of Physics , Virginia Commonwealth University , 701 W. Grace St. , Richmond , Virginia 23284 , USA . Email: snkhanna@vcu.edu.
Zhaoguo ZhuDepartment of Chemistry , Johns Hopkins University , Baltimore , Maryland 21218 , USA . Email: kbowen@jhu.edu.
Alexander P AydtDepartment of Chemistry , Columbia University , New York , New York 10027 , USA . Email: xr2114@columbia.edu.
Shiv N KhannaDepartment of Physics , Virginia Commonwealth University , 701 W. Grace St. , Richmond , Virginia 23284 , USA . Email: snkhanna@vcu.edu.ORCID 0000-0002-9797-1289
Xavier RoyDepartment of Chemistry , Columbia University , New York , New York 10027 , USA . Email: xr2114@columbia.edu.ORCID 0000-0002-8850-0725
Kit H BowenDepartment of Chemistry , Johns Hopkins University , Baltimore , Maryland 21218 , USA . Email: kbowen@jhu.edu.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Molecular clusters are attractive superatomic building blocks for creating materials with tailored properties due to their unique combination of atomic precision, tunability and functionality. The ligands passivating these superatomic clusters offer an exciting opportunity to control their electronic properties while preserving their closed shells and electron counts, which is not achievable in conventional atoms. Here we demonstrate this concept by measuring the anion photoelectron spectra of a series of hexanuclear cobalt sulfide superatomic clusters with different ratios of electron-donating and electron-withdrawing ligands, Co

Identifiers

PMID30842842
PMCPMC6369407

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.