ArticleAngewandte Chemie (International ed. in English)2019
Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
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Who cites it
32 citing papers in PubMed.
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- Iron-Catalyzed Tunable Double Bond Migration and Geometrical Isomerization in Olefins via a Spin-Accelerated Alkyl Mechanism.Angewandte Chemie (International ed. in English) · 2025Article
- HighlyThe Journal of organic chemistry · 2025Article
- Stereospecific positional alkene isomerization enables bidirectional central-to-axial chirality transfer.Nature communications · 2025Article
- Kinetics, Thermodynamics, and Emergence in Stereoediting Reactions.Accounts of chemical research · 2025Article
- NJACS Au · 2024Article
- Alkene Isomerization Catalyzed by a Mn(I) Bisphosphine Borohydride Complex.ACS catalysis · 2024Article
- Exploring the Potential of Al(III) Photosensitizers for Energy Transfer Reactions.Inorganic chemistry · 2024Article
- A Neutral PCThe Journal of organic chemistry · 2024Article
- Characterization of the Reversible Intersystem Crossing Dynamics of Organic Photocatalysts Using Transient Absorption Spectroscopy and Time-Resolved Fluorescence Spectroscopy.The journal of physical chemistry. A · 2023Article
- B(CChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Rh-catalyzed regio-switchable cross-coupling ofChemical science · 2022Article
- Switching between Hydrogenation and Olefin Transposition Catalysis via Silencing NH Cooperativity in Mn(I) Pincer Complexes.ACS catalysis · 2022Article
- Highly selective acid-catalyzed olefin isomerization of limonene to terpinolene by kinetic suppression of overreactions in a confined space of porous metal-macrocycle frameworks.Chemical science · 2022Article
- Unified, Asymmetric Total Synthesis of the Asnovolins and Related Spiromeroterpenoids: A Fragment Coupling Approach.Journal of the American Chemical Society · 2022Article
- Decoding Key Transient Inter-Catalyst Interactions in a Reductive Metallaphotoredox-Catalyzed Allylation Reaction.Journal of the American Chemical Society · 2022Article
- Nickel catalyzed multicomponent stereodivergent synthesis of olefins enabled by electrochemistry, photocatalysis and photo-electrochemistry.Nature communications · 2022Article
- Metal-Free Photochemical Olefin Isomerization of Unsaturated Ketones via 1,5-Hydrogen Atom Transfer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.Chemical reviews · 2022Review
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4 authors.
Funding
Abstract
We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the ligand, the most stable isomers are obtained, while isomerizing terminal alkenes over one position can be selectively controlled by using DPEphos as the ligand. The presence of the donor-acceptor dye 4CzIPN accelerates the reaction further. Transformation of exocyclic alkenes into the corresponding endocyclic products could be efficiently realized by using 4CzIPN and Co(acac)
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