ArticleJournal of the American Chemical Society2019
Designed Conformation and Fluorescence Properties of Self-Assembled Phenazine-Cored Platinum(II) Metallacycles.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- A Vibration-Induced Emission-Based Ratiometric Sensor for Detection of Anions in Aqueous Solution.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
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- Solvation controlled excited-state dynamics in a donor-acceptor phenazine-imidazole derivative.RSC advances · 2024Article
- Tuning vibration-induced emission through macrocyclization and catenation.Chemical science · 2024Article
- Cross-catenation between position-isomeric metallacages.Nature communications · 2024Article
- Modulating the Luminescence, Photosensitizing Properties, and Mitochondria-Targeting Ability of D-π-A-Structured Dihydrodibenzo[Molecules (Basel, Switzerland) · 2023Article
- Tailor-Made Dynamic Fluorophores: Precise Structures Controlling the Photophysical Properties.Precision chemistry · 2023Review
- Phenylthiol-BODIPY-based supramolecular metallacycles for synergistic tumor chemo-photodynamic therapy.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- A Vibration-Induced-Emission-Based Fluorescent Chemosensor for the Selective and Visual Recognition of Glucose.Angewandte Chemie (International ed. in English) · 2021Article
- Self-assembled metallasupramolecular cages towards light harvesting systems for oxidative cyclization.Chemical science · 2021Article
- The endeavor of vibration-induced emission (VIE) for dynamic emissions.Chemical science · 2020Review
- Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination.Chemical Society reviews · 2020Article
- A cyclic bis[2]catenane metallacage.Nature communications · 2020Article
- Color-tunable single-fluorophore supramolecular system with assembly-encoded emission.Nature communications · 2020Article
- Self-Assembled Fluorescent Pt(II) Metallacycles as Artificial Light-Harvesting Systems.Journal of the American Chemical Society · 2019Article
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Authors and funding
7 authors.
Funding
Abstract
A series of platinum(II) metallacycles were prepared via the coordination-driven self-assembly of a phenazine-cored dipyridyl donor with a 90° Pt(II) acceptor and various dicarboxylate donors in a 1:1:2 ratio. While the metallacycles display similar absorption profiles, they exhibit a trend of blue-shifted fluorescence emission with the decrease in the bite angles between the carboxylate building blocks. Comprehensive spectroscopic and dynamic studies as well as a computational approach were conducted, revealing that the difference in the degree of constraint imposed on the excited-state planarization of the phenazine core within these metallacycles results in their distinct photophysical behaviors. As such, a small initial difference in the dicarboxylate building blocks is amplified into distinct photophysical properties of the metallacycles, which is reminiscent of the efficient functional tuning observed in natural systems. In addition to the pre-assembly approach, the photophysical properties of a metallacycle can also be modulated using a post-assembly modification to the dicarboxylate building block, suggesting another strategy for functional tuning. This research illustrated the potential of coordination-driven self-assembly for the preparation of materials with precisely tailored functionalities at the molecular level.
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