ArticleNature communications2019
Probing hydrogen bond strength in liquid water by resonant inelastic X-ray scattering.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Real-time tracking of the intramolecular vibrational dynamics of liquid water.Communications chemistry · 2026Article
- Resonant Inelastic X-ray Scattering: How Well Does LR-TDDFT Perform?The journal of physical chemistry. A · 2025Article
- Symmetry Breaking around Aqueous Ammonia Revealed in Nitrogen K-edge X-ray Absorption.The journal of physical chemistry letters · 2025Article
- Observation of an Associative State in Aqueous Hydroxide.Journal of the American Chemical Society · 2025Article
- The Heisenberg-RIXS instrument at the European XFEL.Journal of synchrotron radiation · 2025Article
- Dynamic anti-correlations of water hydrogen bonds.Nature communications · 2024Article
- Understanding X-ray absorption in liquid water using triple excitations in multilevel coupled cluster theory.Nature communications · 2024Article
- Measurement of coherent vibrational dynamics with X-ray Transient Absorption Spectroscopy simultaneously at the Carbon K- and Chlorine LCommunications physics · 2024Article
- Solvation, Surface Propensity, and Chemical Reactions of Solutes at Atmospheric Liquid-Vapor Interfaces.Accounts of chemical research · 2022Article
- Cuts through the manifold of molecular HProceedings of the National Academy of Sciences of the United States of America · 2022Article
- Emulator-based decomposition for structural sensitivity of core-level spectra.Royal Society open science · 2022Article
- Hole Dynamics in Photoexcited Hematite Studied with Femtosecond Oxygen K-edge X-ray Absorption Spectroscopy.The journal of physical chemistry letters · 2022Article
- Targeting Individual Tautomers in Equilibrium by Resonant Inelastic X-ray Scattering.The journal of physical chemistry letters · 2022Article
- Breaking the Symmetry of Pyrimidine: Solvent Effects and Core-Excited State Dynamics.The journal of physical chemistry letters · 2021Article
- Sensitivity of Nitrogen K-Edge X-ray Absorption to Halide Substitution and Thermal Fluctuations in Methylammonium Lead-Halide Perovskites.The journal of physical chemistry. C, Nanomaterials and interfaces · 2021Article
- Vibrational resonant inelastic X-ray scattering in liquid acetic acid: a ruler for molecular chain lengths.Scientific reports · 2021Article
- Characterization of the soft X-ray spectrometer PEAXIS at BESSY II.Journal of synchrotron radiation · 2020Article
- Reply to Pettersson et al.: Why X-ray spectral features are compatible to continuous distribution models in ambient water.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
- Do X-ray spectroscopies provide evidence for continuous distribution models of water at ambient conditions?Proceedings of the National Academy of Sciences of the United States of America · 2019Article
Corrections and comments
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Authors and funding
17 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Local probes of the electronic ground state are essential for understanding hydrogen bonding in aqueous environments. When tuned to the dissociative core-excited state at the O1s pre-edge of water, resonant inelastic X-ray scattering back to the electronic ground state exhibits a long vibrational progression due to ultrafast nuclear dynamics. We show how the coherent evolution of the OH bonds around the core-excited oxygen provides access to high vibrational levels in liquid water. The OH bonds stretch into the long-range part of the potential energy curve, which makes the X-ray probe more sensitive than infra-red spectroscopy to the local environment. We exploit this property to effectively probe hydrogen bond strength via the distribution of intramolecular OH potentials derived from measurements. In contrast, the dynamical splitting in the spectral feature of the lowest valence-excited state arises from the short-range part of the OH potential curve and is rather insensitive to hydrogen bonding.
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