ArticleNature communications2019
Atomic insight into hydration shells around facetted nanoparticles.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. It has been retracted, and should not be counted. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Article
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- Effects of Cosolvent on the Intermolecular Interactions between an Analyte and a Gold Nanostar Surface Studied Using SERS.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Nanoplastics in Water: Artificial Intelligence-Assisted 4D Physicochemical Characterization and Rapid In Situ Detection.Environmental science & technology · 2024Article
- The local ordering of polar solvents around crystalline carbon nitride nanosheets in solution.Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2023Article
- A hierarchical spatial assembly approach of silica-polymer composites leads to versatile silica/carbon nanoparticles.Science advances · 2023Article
- Beam-induced redox chemistry in iron oxide nanoparticle dispersions at ESRF-EBS.Journal of synchrotron radiation · 2023Article
- The Crucial Role of Solvation Forces in the Steric Stabilization of Nanoplatelets.Nano letters · 2022Article
- Antihypertension Nanoblockers Increase Intratumoral Perfusion of Sequential Cytotoxic Nanoparticles to Enhance Chemotherapy Efficacy against Pancreatic Cancer.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Iron oxide nanoflowers encapsulated in thermosensitive fluorescent liposomes for hyperthermia treatment of lung adenocarcinoma.Scientific reports · 2022Article
- Structural Analysis of Molecular Materials Using the Pair Distribution Function.Chemical reviews · 2022Review
- Pair distribution function andChemical science · 2021Article
- Structural Changes during the Growth of Atomically Precise Metal Oxido Nanoclusters from Combined Pair Distribution Function and Small-Angle X-ray Scattering Analysis.Angewandte Chemie (International ed. in English) · 2021Article
- Article
- X-ray scattering reveals ion clustering of dilute chromium species in molten chloride medium.Chemical science · 2021Article
- Synthesis and Characterization of Amorphous Iron Oxide Nanoparticles by the Sonochemical Method and Their Application for the Remediation of Heavy Metals from Wastewater.Nanomaterials (Basel, Switzerland) · 2020Article
Corrections and comments
- Retracted
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nanoparticles in solution interact with their surroundings via hydration shells. Although the structure of these shells is used to explain nanoscopic properties, experimental structural insight is still missing. Here we show how to access the hydration shell structures around colloidal nanoparticles in scattering experiments. For this, we synthesize variably functionalized magnetic iron oxide nanoparticle dispersions. Irrespective of the capping agent, we identify three distinct interatomic distances within 2.5 Å from the particle surface which belong to dissociatively and molecularly adsorbed water molecules, based on theoretical predictions. A weaker restructured hydration shell extends up to 15 Å. Our results show that the crystal structure dictates the hydration shell structure. Surprisingly, facets of 7 and 15 nm particles behave like planar surfaces. These findings bridge the large gap between spectroscopic studies on hydrogen bond networks and theoretical advances in solvation science.
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Registered trials
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