Evidence map›Paper›PMID 30786120›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Superelectrophilicity of 1,2-Azaborine: Formation of Xenon and Carbon Monoxide Adducts.

Klara Edel, Jacob S A Ishibashi, Shih-Yuan Liu, Holger F Bettinger

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. A Nitrilium-TypeJournal of the American Chemical Society · 2025
    Article
  3. Article
  4. Article
  5. Superelectrophiles: Recent Advances.Molecules (Basel, Switzerland) · 2020
    Review
  6. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Klara EdelInstitut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany.
Jacob S A IshibashiDepartment of Chemistry, Boston College, Chestnut Hill, Massachusetts, 02467-3860, USA.ORCID 0000-0003-2045-4387
Shih-Yuan LiuDepartment of Chemistry, Boston College, Chestnut Hill, Massachusetts, 02467-3860, USA.ORCID 0000-0003-3148-9147
Holger F BettingerInstitut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany.ORCID 0000-0001-5223-662X

Funding

Development of BN Heterocycles for Biomedical ResearchR01GM094541 · NIGMS · UNIVERSITY OF OREGON · PI LIU, SHIH-YUAN · 2010 to 2019
$2.8M
DFG INST 40/467-1 FUGGNIGMS NIH HHS R01 GM094541
6 · The paper itself

Abstract

The BN analogue of ortho-benzyne, 1,2-azaborine, is shown to bind carbon monoxide and a xenon atom under matrix isolation conditions, demonstrating its strongly Lewis acidic superelectrophilic nature. The Lewis acid-base complexes involving CO and Xe can be cleaved photochemically and reformed by mildly annealing the matrices. The interaction energy of 1,2-azaborine with Xe is 3 kcal mol

Indexed as

Benzene DerivativesBoron CompoundsCarbon MonoxideCycloaddition ReactionLewis BasesMethaneQuantum TheoryXenon1,2-azaborineBenzene DerivativesbenzyneBoron CompoundscarbeneCarbon MonoxideLewis BasesMethaneXenon1,2-azaborinecarbon monoxideLewis acidsmatrix isolationxenon

Identifiers

PMID30786120
PMCPMC6609157

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.