ReviewMolecules (Basel, Switzerland)2019
Synthesis, Physical Properties, and Reactivity of Stable, π-Conjugated, Carbon-Centered Radicals.
Review in Molecules (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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11 citing papers in PubMed.
- Modulating multicenter bonding through facile addition of diradical precursors to a bipyridine-stabilized borane.Chemical science · 2026Article
- Benzo[cd]azulenyl: A Structural Isomer of Phenalenyl-Synthesis and Properties of Its Tri-tert-butyl-substituted Derivative and Formation of a Thermal- and Photoresponsive σ-Dimer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Article
- Cethrene's Catch-22: Is Trading Magnetism for Bistability Inevitable?Organic letters · 2025Article
- A Triplet/Singlet Ground-State Switch via the Steric Inhibition of Conjugation in 4,6-Bis(trifluoromethyl)-1,3-phenylene Bisnitroxide.Molecules (Basel, Switzerland) · 2023Article
- A rational design strategy of radical-type mechanophores with thermal tolerance.Chemical science · 2023Article
- Improving the Luminescence and Stability of Carbon-Centered Radicals by Kinetic Isotope Effect.Molecules (Basel, Switzerland) · 2023Article
- Nanotechnology for brain tumor imaging and therapy based on π-conjugated materials: state-of-the-art advances and prospects.Frontiers in chemistry · 2023Review
- A quantitative metric for organic radical stability and persistence using thermodynamic and kinetic features.Chemical science · 2021Article
- Simultaneous photoadhesion and photopatterning technique for passivation of flexible neural electrodes based on fluoropolymers.Scientific reports · 2020Article
- Aromatic Nanosandwich Obtained by σ-Dimerization of a Nanographenoid π-Radical.Journal of the American Chemical Society · 2020Article
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1 author.
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Abstract
Recently, long-lived, organic radical species have attracted much attention from chemists and material scientists because of their unique electronic properties derived from their magnetic spin and singly occupied molecular orbitals. Most stable and persistent organic radicals are heteroatom-centered radicals, whereas carbon-centered radicals are generally very reactive and therefore have had limited applications. Because the physical properties of carbon-centered radicals depend predominantly on the topology of the π-electron array, the development of new carbon-centered radicals is key to new basic molecular skeletons that promise novel and diverse applications of spin materials. This account summarizes our recent studies on the development of novel carbon-centered radicals, including phenalenyl, fluorenyl, and triarylmethyl radicals.
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