Evidence map›Paper›PMID 30781594›Full record

ArticleMolecules (Basel, Switzerland)2019

Metal-Free Alpha Trifluoromethylselenolation of Carbonyl Derivatives under Batch and Flow Conditions.

Elisabetta Massolo, Margherita Pirola, Sergio Rossi, Tiziana Benincori

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Elisabetta MassoloDipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133 Milano, Italy. elisabetta.massolo@unimi.it.
Margherita PirolaDipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133 Milano, Italy. margherita.pirola@unimi.it.
Sergio RossiDipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133 Milano, Italy. Sergio.rossi@unimi.it.ORCID 0000-0002-2694-9535
Tiziana BenincoriDipartimento di Scienza e Alta Tecnologia, Università degli Studi Dell'Insubria, Via Valleggio 11, 22100 Como, Italy. tiziana.benincori@uninsubria.it.

Funding

Piano Sostegno alla Ricerca PSR2017
6 · The paper itself

Abstract

Trifluoromethylselenolated carbonyl compounds represent an emerging class with potential applications in several fields; however, a widespread use of such compound is hampered by the very limited number of strategies for their preparation. In this study we developed a method for the preparation of α-SeCF₃ substituted carbonyl derivatives using an in situ generated electrophilic ClSeCF₃ species. We also implemented an in-flow protocol to improve the safety features of the process.

Indexed as

Hydrocarbons, FluorinatedMolecular StructureOrganoselenium CompoundsOxidation-ReductionSolventsTemperatureHydrocarbons, FluorinatedOrganoselenium CompoundsSolventscarbonyl compoundsflow chemistryfluorinated derivativesseleniumtrifluoromethylselenolation

Identifiers

PMID30781594
PMCPMC6412565

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.