Evidence map›Paper›PMID 30774903›Full record

ArticleChemical science2019

Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with naphthols: a reaction sequence to larger π-conjugated naphthopyrans with aggregation-induced emission characters.

Jinlong Zhang, Lu Zhu, Kang Shen, Huameng Yang, Xiao-Chun Hang, Gaoxi Jiang

Abstract read
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Jinlong ZhangState Key Laboratory for Oxo Synthesis and Selective Oxidation , Center for Excellence in Molecular Synthesis , Suzhou Research Institute of LICP , Lanzhou Institute of Chemical Physics (LICP) , Chinese Academy of Sciences , Lanzhou 730000 , China . Email: gxjiang@licp.cas.cn.
Lu ZhuKey Laboratory of Flexible Electronics (KLOFE) , Institute of Advanced Materials (IAM) , Nanjing Tech University (NanjingTech) , 30 South Puzhu Road , Nanjing 211800 , China . Email: iamxchhang@njtech.edu.cn.
Kang ShenKey Laboratory of Flexible Electronics (KLOFE) , Institute of Advanced Materials (IAM) , Nanjing Tech University (NanjingTech) , 30 South Puzhu Road , Nanjing 211800 , China . Email: iamxchhang@njtech.edu.cn.
Huameng YangState Key Laboratory for Oxo Synthesis and Selective Oxidation , Center for Excellence in Molecular Synthesis , Suzhou Research Institute of LICP , Lanzhou Institute of Chemical Physics (LICP) , Chinese Academy of Sciences , Lanzhou 730000 , China . Email: gxjiang@licp.cas.cn.
Xiao-Chun HangKey Laboratory of Flexible Electronics (KLOFE) , Institute of Advanced Materials (IAM) , Nanjing Tech University (NanjingTech) , 30 South Puzhu Road , Nanjing 211800 , China . Email: iamxchhang@njtech.edu.cn.
Gaoxi JiangState Key Laboratory for Oxo Synthesis and Selective Oxidation , Center for Excellence in Molecular Synthesis , Suzhou Research Institute of LICP , Lanzhou Institute of Chemical Physics (LICP) , Chinese Academy of Sciences , Lanzhou 730000 , China . Email: gxjiang@licp.cas.cn.ORCID 0000-0003-1555-1107

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A practical and readily scalable reaction sequence was developed for the straightforward synthesis of a new family of larger π-conjugated naphthopyrans by a Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with inert naphthols. The cascade pathway involves allylation/cyclization/debenzyloxylation/isomerization/dehydration. The new class of solid state diphenylmethylene substituted naphthopyrans are fluorescent emissive and proved to have aggregation-induced emission (AIE) behavior.

Identifiers

PMID30774903
PMCPMC6346396

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.