ArticleChemical science2019
X-ray Raman optical activity of chiral molecules.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
5 citing papers in PubMed.
- Time-Resolved Circular Dichroism in Molecules: Experimental and Theoretical Advances.Molecules (Basel, Switzerland) · 2024Review
- Time-resolved enantiomer-exchange probed by using the orbital angular momentum of X-ray light.Chemical science · 2023Article
- Ultrafast chirality: the road to efficient chiral measurements.Physical chemistry chemical physics : PCCP · 2022Review
- Pathways to increase the dissymmetry in the interaction of chiral light and chiral molecules.Chemical science · 2021Review
- Real-time probing of chirality during a chemical reaction.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Resonant and off-resonant Raman Optical Activity signals in the X-ray regime (XROA) are predicted. XROA is a chiral-sensitive variant of the spontaneous Resonant Inelastic Scattering (RIXS) signal. Thanks to the highly localized nature of core excitations, these signals provide a direct probe of local chirality with high sensitivity to the molecular structure. We derive sum-over-states expressions for frequency domain XROA signals and apply them to tyrosine at the nitrogen and oxygen K-edges. Time-resolved extensions of ROA made possible by using additional pulses are briefly outlined.
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Registered trials
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