ArticleChemical science2019
Do water's electrons care about electrolytes?
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
13 citing papers in PubMed, 42 citations in OpenAlex.
- Unraveling the Molecular Pathways for Structure "Making" and "Breaking" by Ions in Water.Journal of the American Chemical Society · 2025Article
- The solvation shell probed by resonant intermolecular Coulombic decay.Nature communications · 2024Article
- Liquid-jet photoemission spectroscopy as a structural tool: site-specific acid-base chemistry of vitamin C.Physical chemistry chemical physics : PCCP · 2024Article
- How Does MgJournal of the American Chemical Society · 2024Article
- Specific versus Nonspecific Solvent Interactions of a Biomolecule in Water.The journal of physical chemistry letters · 2023Article
- How to measure work functions from aqueous solutions.Chemical science · 2023Article
- Absolute Electronic Energetics and Quantitative Work Functions of Liquids from Photoelectron Spectroscopy.Accounts of chemical research · 2023Article
- Photoionization of the aqueous phase: clusters, droplets and liquid jets.Physical chemistry chemical physics : PCCP · 2022Review
- Probing aqueous ions with non-local Auger relaxation.Physical chemistry chemical physics : PCCP · 2022Article
- Quantitative electronic structure and work-function changes of liquid water induced by solute.Physical chemistry chemical physics : PCCP · 2022Article
- Following in Emil Fischer's Footsteps: A Site-Selective Probe of Glucose Acid-Base Chemistry.The journal of physical chemistry. A · 2021Article
- Accurate vertical ionization energy and work function determinations of liquid water and aqueous solutions.Chemical science · 2021Article
- Core and Valence Level Photoelectron Spectroscopy of Nanosolvated KCl.The journal of physical chemistry. A · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Ions have a profound effect on the geometrical structure of liquid water and an aqueous environment is known to change the electronic structure of ions. Here we combine photoelectron spectroscopy measurements from liquid microjets with molecular dynamical and quantum chemical calculations to address the reverse question, to what extent do ions affect the electronic structure of liquid water? We study aqueous solutions of sodium iodide (NaI) over a wide concentration range, from nearly pure water to 8 M solutions, recording spectra in the 5 to 60 eV binding energy range to include all water valence and the solute Na
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.