ArticleNature communications2019
Stable radical anions generated from a porous perylenediimide metal-organic framework for boosting near-infrared photothermal conversion.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 56 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
56 citing papers in PubMed, 436 citations in OpenAlex.
- Persistent Halogenated Perylenediimide Organic Radical Anions Orchestrating Three-Photon Energy Conversion and Programmable Molecular Coupling.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Multifunctional metal-organic frameworks for direct photosynthesis of cyclic carbonates from gaseous olefins.Nature communications · 2026Article
- Narrow-Bandgap Donor-Acceptor Polymers for Efficient Solar Water Evaporation and Thermoelectric Power Generation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Sustaining Radicals in Aqueous Media Through Formation of a Trigger-Inclusive Microenvironment in Hydrogen-Bonded Frameworks for Antibacterial Activity.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Super-stable two-dimensional radical conjugated metal-organic frameworks for efficient NIR-II photothermal conversion.Science advances · 2026Article
- CRISPR/Cas9-Based Vanadium MXene-Free Radical Spatiotemporally Controlled Nanoreactor for Photothermal-Induced Multi-Effect Synergistic Antitumor Therapy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Chromatic-Invariant Photothermal Fabrics Enabled by Narrow-Bandgap Organic Semiconductors for Wearable Solar Energy Harvesting.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Metal-Organic Frameworks for Precision Phototherapy of Breast Cancer.Molecules (Basel, Switzerland) · 2026Review
- Development of hybrid nanoparticles based on Zr(iv) and perylene-3,4,9,10-tetracarboxylic acid with visible-light photoredox activity.RSC advances · 2026Article
- Application of MOFs-mediated phototherapy in cancer treatment.RSC advances · 2025Review
- Recent Developments in Organic Radical Inclusion in MOFs and Radical MOFs.ChemistryOpen · 2025Review
- Redox-bipolar mesoporous two-dimensional covalent organic framework for multi-color electrochromism.Science advances · 2025Article
- Spontaneous amino-yne click polymerization enabled by pyridinium-activated alkynes toward p-π conjugated ionic polymers.Chemical science · 2025Article
- Dibenzononazethrene Isomers: Stable Singlet Diradicaloids with Efficient Photothermal Conversion.Precision chemistry · 2025Article
- Engineering Bodipy-Based Metal-Organic Frameworks for Efficient Full-Spectrum Photocatalysis in Amide Synthesis.Angewandte Chemie (International ed. in English) · 2025Article
- Hierarchical Assembly of Carbon Dots with Full-Solar-Spectrum Absorption for Solar Energy Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- NIR-II Emissive Persistent Neutral π-Radical with Rapid Doublet Internal Conversion for Efficient Cancer Photothermal Theranostics.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Aggregation induced emission luminogen bacteria hybrid bionic robot for multimodal phototheranostics and immunotherapy.Nature communications · 2025Article
- Enhancing Electron Donor-Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Deciphering a volcano-shaped relationship between radical stability and reticular electrochemiluminescence.Nature communications · 2025Article
Corrections and comments
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Authors and funding
6 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Radical anions of electron-deficient systems are widely used, but are easily reoxidized upon exposure to air. Therefore, the stabilization of radical anions under ambient conditions is of great significance, but still remains a scientific challenge. Herein, perylenediimide is employed to prepare a crystalline metal-organic framework for stabilizing radical anions without extensive chemical modification. The porous, three-dimensional framework of perylenediimide can trap electron donors such as amine vapors and produce radical anions in-situ through photo-induced electron transfer. The radical anions are protected against quenching by shielding effect in air and remain unobstructed in air for at least a month. Because of the high yield and stability of the radical anions, which are the basis for near-infrared photothermal conversion, the framework shows high near-infrared photothermal conversion efficiency (η = 52.3%). The work provides an efficient and simple method towards ambient stable radical anions and affords a promising material for photothermal therapy.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.