ArticleNature reviews. Chemistry2018
Earth-Abundant Transition Metal Catalysts for Alkene Hydrosilylation and Hydroboration: Opportunities and Assessments.
Article in Nature reviews. Chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 130 papers.
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Who cites it
130 citing papers in PubMed.
- Recyclable Pt-Catalyzed Biphase Hydrosilylation on Water: From Functionalized Monomers to Polymer Materials.Angewandte Chemie (International ed. in English) · 2026Article
- Copper Nanoclusters with Exposed Active Sites for Highly Efficient Protoboration of C-C Multiple Bonds.Molecules (Basel, Switzerland) · 2026Article
- Three-site cycloadditions within one reaction intermediate with site-selectivity controlled by electronic and size bias.Nature communications · 2026Article
- Controllable Hydrosilylation and Dehydrogenative Silylation of Alkenes Catalyzed by a Manganese Alkyl Complex.Organometallics · 2026Article
- On the Electronic Nature of Open-Shell Germylene Complexes of MInorganic chemistry · 2026Article
- Regiodivergent Hydrosilylation of Alkenes at Nickel: Tuning the Selectivity by Complex Stoichiometry and Silane Identity.Inorganic chemistry · 2026Article
- Dual Photoredox/Cobalt Catalysis Enabled Regiospecific Markovnikov Hydroboration of Unactivated Mono-, Di-, and Trisubstituted Alkenes.Nature communications · 2026Article
- Contra-Thermodynamic Chain-Walking Isomerization: A Sustainable Tool for Selective Molecular Editing in Green Chemistry.ChemSusChem · 2026Article
- Precise borylation of targeted methyl group via an orderly chain-walking strategy.Science advances · 2026Article
- NiH-Catalyzed Enantioconvergent α-Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation.Angewandte Chemie (International ed. in English) · 2026Article
- Engineering MXenes for Thermal and Photothermal Catalysis.Chemical reviews · 2026Review
- Carbonaceous supports for Schiff base metal complexes: Strategies for enhanced catalytic efficiency.iScience · 2026Review
- Synthesis and Characterization of Unusual S=1 Fe(0)-Silyl Complexes Supported by Styrene Ligands.Angewandte Chemie (International ed. in English) · 2026Article
- Enhanced methane chlorination via RuONature communications · 2026Article
- Electrochemical desulfurative borylation of thiols, disulfides, thioethers and thioacetals.Nature communications · 2026Article
- Article
- Air-Stable Cobalt-Semiquinone Radical Complexes on Carbon Nanotubes: A Redox Switch for Anion Response.Journal of the American Chemical Society · 2025Article
- Markovnikov-Selective Hydroboration of Aryl Alkenes Catalyzed by Quaternary Ammonium Salts.Journal of the American Chemical Society · 2025Article
- Catalytic ester hydroboration promoted by actinide complexes featuring six-membered N-heterocyclic imine ligands and actinide-alkoxides activation.Communications chemistry · 2025Article
- Catalyst-controlled stereodivergent synthesis of polysubstituted alkenes.Nature communications · 2025Article
70 more citing papers are in PubMed but not listed here.
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Authors and funding
2 authors.
Funding
Abstract
The addition of a silicon-hydrogen or a boron-hydrogen bond across a carbon-carbon multiple bonds is a well-established method for the introduction of versatile silane and borane functional groups to base hydrocarbon feedstocks. Transition metal catalysis, historically with precious second- and third- row transition metals, has been used to broaden the scope of the hydrofunctionalization reaction, improve reaction rate and enhance selectivity. The anti-Markovnikov selectivity of platinum-catalyzed hydrosilylation of alkenes, for example, is an enabling synthetic technology in the multibillion-dollar silicones industry. Increased emphasis on sustainable catalytic methods and more economic processes has shifted focus to catalysis with more earth-abundant transition metals such as iron, cobalt and nickel. This review describes contemporary approaches and offers a contextual analysis of catalytic alkene hydrosilylation and hydroboration reactions using first-row transition metals. Emphasis is placed on defining advances in the field, what constitutes catalyst cost, safety, and important design features to enable precious metal-like reactivity, as well as new chemistry that is unique to first-row transition metals.
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Registered trials
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