ArticleACS catalysis2018
Catalytic, Enantioselective Synthesis of Allenyl Boronates.
Article in ACS catalysis, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed.
- Diastereoselective Synthesis of Axially Chiral Skipped Ene-Allenes Containing a Quaternary Stereocenter by Cyclopropene-Allene Metathesis.Angewandte Chemie (International ed. in English) · 2026Article
- Copper-Catalyzed Asymmetric Hydroboration of Cyclic Dienes.Chemistry, an Asian journal · 2026Article
- Electrochemical synthesis of allenyl silanes and allenyl boronic esters.Nature communications · 2025Article
- Exploring the capabilities of 2-alkynyl aryl/benzyl azides: synthesis approaches for indoles, quinolines, and their derivativesRSC advances · 2025Review
- Axially chiral α-boryl-homoallenyl boronic esters as versatile toolbox for accessing centrally and axially chiral molecules.Nature communications · 2024Article
- Chemo-, Regio-, and StereoselectiveOrganic letters · 2024Article
- NHC-Au-Catalyzed Isomerization of Propargylic B(MIDA)s to Allenes and Double Isomerization of Alkynes to 1,3-Dienes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Copper(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of 1,3-enynes and azomethine ylides.Nature communications · 2023Article
- A Pd-catalyzed highly selective three-component protocol for trisubstituted allenes.Chemical science · 2023Article
- Iron-Catalyzed Borylation of Propargylic Acetates for the Synthesis of Multisubstituted Allenylboronates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates.Molecules (Basel, Switzerland) · 2022Review
- Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water.RSC advances · 2022Article
- Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols.Angewandte Chemie (International ed. in English) · 2021Article
- Decarboxylative 1,4-carbocyanation of 1,3-enynes to access tetra-substituted allenesChemical science · 2021Article
- Generation of Axially Chiral Fluoroallenes through a Copper-Catalyzed Enantioselective β-Fluoride Elimination.Journal of the American Chemical Society · 2021Article
- Halogenated salt assisted Cu-catalyzed asymmetric 1,4-borylstannation of 1,3-enynes: enantioselective synthesis of allenylstannes.Chemical science · 2020Article
- Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C-C, C-B, C-H, and C-Si Bonds.Angewandte Chemie (International ed. in English) · 2020Review
- Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes.Nature communications · 2020Article
- Asymmetric synthesis of γ-chiral borylalkanesChemical science · 2020Article
- Synthesis of Pyrroles through the CuH-Catalyzed Coupling of Enynes and Nitriles.Journal of the American Chemical Society · 2020Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
A method to achieve enantioselective 1,4-hydroboration of terminal enynes to access allenyl boronates under CuH catalysis is described. The reaction typically proceeds in a highly stereoselective manner and tolerates an array of synthetically useful functional groups. The utility of the enantioenriched allenyl boronate products is demonstrated through several representative downstream derivatizations.
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Registered trials
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