ArticleNature communications2019
Electrooxidative para-selective C-H/N-H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Mechanochemical Dehydrogenative Phenochalcogenazination: A Pronounced Water Effect.ChemSusChem · 2026Article
- Intercepting Photogenerated Aminyl Radicals at Metal-Halide Perovskite Microcrystals to Forge C─N Bonds With Non-Preactivated Substrates.Small science · 2026Article
- Electrochemical oxidation enables aromatic C-H amination with dual mechanisms.Nature synthesis · 2026Article
- Electropolymerization of Silver(I) Helicate into Conductive Metallopolymer: Structural and Functional Insights.Inorganic chemistry · 2025Article
- Electrochemical Approach to Organonitrogen Compounds via C-N Coupling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Screening and dissecting electroorganic synthesis by mass spectrometry decoupling of electrode and homogeneous processes.Nature communications · 2025Article
- Interfacial electromigration for accelerated reactions.Analytica chimica acta · 2025Article
- Electrochemical Non-Directed Arene C-H Amination.ChemCatChem · 2024Article
- Site-Selective Electrochemical Arene C-H Amination.Journal of the American Chemical Society · 2024Article
- Electro-oxidative quinylation of sulfides to sulfur ylides in batch and continuous flow.iScience · 2024Article
- Electrochemical flow aziridination of unactivated alkenes.National science review · 2023Article
- Aqueous pulsed electrochemistry promotes C-N bond formation via a one-pot cascade approach.Nature communications · 2023Article
- Efficient and Selective Photogeneration of Stable N-Centered Radicals via Controllable Charge Carrier Imbalance in Cesium Lead Halide Nanocrystals.Journal of the American Chemical Society · 2023Article
- Metal-free C-3 selective C(spRSC advances · 2023Article
- Mechanistic Aspects of the Electrochemical Oxidation of Aliphatic Amines and Aniline Derivatives.Molecules (Basel, Switzerland) · 2023Review
- Insights into electrochemiluminescence dynamics by synchronizing real-time electrical, luminescence, and mass spectrometric measurements.Chemical science · 2022Article
- Construction of C-N bonds from small-molecule precursors through heterogeneous electrocatalysis.Nature reviews. Chemistry · 2022Review
- Iron-Catalyzed Oxidative C-O and C-N Coupling Reactions Using Air as Sole Oxidant.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- OThe Journal of organic chemistry · 2022Article
- Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines.Organic letters · 2022Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Oxidative C-H/N-H cross-coupling is one of the most atom-economical methods for the construction of C-N bonds. However, traditional oxidative C-H/N-H cross-coupling either required the use of strong oxidants or high reaction temperature, which makes it difficult to tolerate redox active functional groups. Herein we describe an external chemical oxidant-free electrooxidative C-H/N-H cross-coupling between electron-rich arenes and diarylamine derivatives. Under undivided electrolytic conditions, a series of triarylamine derivatives are produced from electron-rich arenes and diarylamine derivatives with high functional group tolerance. Both of the coupling partners are redox active in oxidative C-H/N-H cross-coupling, which enables high regioselectivity in C-N bond formation. Exclusive para-selectivity is observed for the coupling with anilines.
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