ArticleProceedings of the National Academy of Sciences of the United States of America2019
Visualizing the iron atom exchange front in the Fe(II)-catalyzed recrystallization of goethite by atom probe tomography.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 70 citations in OpenAlex.
- Isotopic Exchange between Aqueous Fe(II) and Solid Fe(III) in Lake Sediment─A Kinetic Assemblage Approach.Environmental science & technology · 2025Article
- Model-Based Analysis of Arsenic Retention by Stimulated Iron Mineral Transformation under Coastal Aquifer Conditions.ACS ES&T water · 2024Article
- Natural flavonoids disrupt bacterial iron homeostasis to potentiate colistin efficacy.Science advances · 2023Article
- Understanding the mechanisms of anisotropic dissolution in metal oxides by applying radiolysis simulations to liquid-phase TEM.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Resolving protein-mineral interfacial interactions duringMaterials today. Advances · 2023Article
- Coexisting Goethite Promotes Fe(II)-Catalyzed Transformation of Ferrihydrite to Goethite.Environmental science & technology · 2022Article
- In situ arsenic immobilisation for coastal aquifers using stimulated iron cycling: Lab-based viability assessment.Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry · 2022Article
- Rapid oxygen exchange between hematite and water vapor.Nature communications · 2021Article
- Atom probe tomography.Nature reviews. Methods primers · 2021Article
- Further insights into the Fe(ii) reduction of 2-line ferrihydrite: a semiNanoscale advances · 2020Article
- Linking Isotope Exchange with Fe(II)-Catalyzed Dissolution of Iron(hydr)oxides in the Presence of the Bacterial Siderophore Desferrioxamine-B.Environmental science & technology · 2020Article
Corrections and comments
- Erratum issued
Authors and funding
8 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The autocatalytic redox interaction between aqueous Fe(II) and Fe(III)-(oxyhydr)oxide minerals such as goethite and hematite leads to rapid recrystallization marked, in principle, by an atom exchange (AE) front, according to bulk iron isotopic tracer studies. However, direct evidence for this AE front has been elusive given the analytical challenges of mass-resolved imaging at the nanoscale on individual crystallites. We report successful isolation and characterization of the AE front in goethite microrods by 3D atom probe tomography (APT). The microrods were reacted with Fe(II) enriched in tracer
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