ArticleDalton transactions (Cambridge, England : 2003)2019
A convenient method for the generation of {Rh(PNP)}
Article in Dalton transactions (Cambridge, England : 2003), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Solvent-Dependent Carbon-to-Metal Hydrogen Atom Transfer Reactivity of a Square Planar Rhodium(II) Alkynyl Complex.Organometallics · 2026Article
- Capture of mechanically interlocked molecules by rhodium-mediated terminal alkyne dimerisation.RSC advances · 2024Article
- Iridium complexes of anDalton transactions (Cambridge, England : 2003) · 2023Article
- Oxidative Addition of C-Cl Bonds to a Rh(PONOP) Pincer Complex.Organometallics · 2022Article
- Nucleophilic Reactivity at a ═CH Arm of a Lutidine-Based CNC/Rh System: Unusual Alkyne and COInorganic chemistry · 2022Article
- ηInorganic chemistry · 2021Article
- DFT calculations bring insight to internal alkyne-to-vinylidene transformations at rhodium PNP- and PONOP-pincer complexes.RSC advances · 2021Article
- Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex.European journal of inorganic chemistry · 2020Article
- Rhodium(I) Pincer Complexes of Nitrous Oxide.Angewandte Chemie (International ed. in English) · 2019Article
- Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes.Inorganic chemistry · 2019Article
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Authors and funding
3 authors.
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Abstract
The substitution reactions of [Rh(COD)2][BArF4] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F2C6H4 are shown to be an operationally simple method for the generation of reactive formally 14 VE rhodium(i) adducts in solution. Application of this methodology enables synthesis of known adducts of CO, N2, H2, previously unknown water complexes, and novel vinylidene derivatives [Rh(pincer)(CCHR)][BArF4] (R = tBu, 3,5-tBu2C6H3), through reversible reactions with terminal alkynes.
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Registered trials
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