ArticleNature communications2019
-60 °C solution synthesis of atomically dispersed cobalt electrocatalyst with superior performance.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed, 140 citations in OpenAlex.
- Protocol for fabrication and characterization of Fe-SAC@COF for electrocatalytic oxygen evolution reaction.STAR protocols · 2022Article
- Recent Advances in Strategies for Improving the Performance of COSmall science · 2021Article
- Metal-Based Nanocatalysts via a Universal Design on Cellular Structure.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Article
- Recent Advances in Single-Atom Electrocatalysts for Oxygen Reduction Reaction.Research (Washington, D.C.) · 2020Review
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Authors and funding
11 authors at 6 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Temperature can govern morphologies, structures and properties of products from synthesis in solution. A reaction in solution at low temperature may result in different materials than at higher temperature due to thermodynamics and kinetics of nuclei formation. Here, we report a low-temperature solution synthesis of atomically dispersed cobalt in a catalyst with superior performance. By using a water/alcohol mixed solvent with low freezing point, liquid-phase reduction of a cobalt precursor with hydrazine hydrate is realized at -60 °C. A higher energy barrier and a sluggish nucleation rate are achieved to suppress nuclei formation; thus atomically dispersed cobalt is successfully obtained in a catalyst for oxygen reduction with electrochemical performance superior to that of a Pt/C catalyst. Furthermore, the atomically dispersed cobalt catalyst is applied in a microbial fuel cell to obtain a high maximum power density (2550 ± 60 mW m
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Registered trials
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